Fluoroaliphatic -thio, -sulfinyl or -sulfonyl substituted bicycloaliphatic amic acid amine salts and compositions and use thereof
申请人:CIBA-GEIGY AG
公开号:EP0138748A1
公开(公告)日:1985-04-24
Fluoroaliphatic-thio, -sulfinyl and -sulfonyl substituted bicycloaliphatic amic amine salts of the formula
where Rf is perfluoroalkyl, R' is alkylene optionally interrupted by -O-, -S- or
where Ra is hydrogen or alkyl, Y is lower alkylene or - 0 -, n is 0-2, R, and Rz are independently hydrogen, lower alkyl,hydroxy-lower alky or together with the nitrogen atom to which they are attached, represent morpholino, R3, R4 and R, are independently hydrogen, lower alkyl, or hydroxy-lower alkyl, R6 is lower alkyl, carboxy- lower alkyl, sulfo-lower alkyl, hydroxy-lower alkyl, benzyl or together with R, and the nitrogen atom to which they are attached represent morpholino, and R is hydrogen or methyl are provided. These salts applied in the form of aqueous solutions, dispersions or emulsions are useful in rendering cellulosic and natural and synthetic polyamide materials oil and water repellent.
式中的
氟代脂族
硫代、亚磺酰基和磺酰基取代的双环脂族
氨基胺盐
其中 Rf 为
全氟烷基,R'为任选由-O-、-S-或-O-、-S-或-S-间断的亚烷基。
其中 Ra 是氢或烷基,Y 是低级亚烷基或-0-,n 是 0-2,R 和 Rz 独立地是氢、低级烷基、羟基-低级烷基或与它们连接的氮原子一起代表吗啉基,R3、R4 和 R 独立地是氢、R6为低级烷基、羧基-低级烷基、磺基-低级烷基、羟基-低级烷基、苄基或与 R 和它们所连接的氮原子一起代表吗啉基,R 为氢或甲基。这些盐以
水溶液、分散体或乳液的形式使用,可使
纤维素、天然和合成聚酰胺材料具有憎油性和憎
水性。