[Co(pyridine-2,3-dicarboxylic acid-2H)(hydrazine)(H2O)] | 752205-11-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: [Co(pyridine-2,3-dicarboxylic acid-2H)(hydrazine)(H2O)]
• 英文别名: [Co(qui)(N2H4)(H2O)]；cobalt(2+);hydrazine;pyridine-2,3-dicarboxylate;hydrate
• CAS: 752205-11-1
• 化学式: C₇H₃NO₄*Co*H₂O*H₄N₂
• 分子量: 274.159
• InChiKey: NTPUDRJXZQDBKL-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -4.2
• 重原子数：
  16.0
• 可旋转键数：
  2.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  176.69
• 氢给体数：
  2.0
• 氢受体数：
  7.0

反应信息

• 作为产物：
  描述：

  cobalt(II) nitrate hexahydrate 、 2,3-吡啶二甲酸 、 一水合肼 以 水 为溶剂， 以80%的产率得到[Co(pyridine-2,3-dicarboxylic acid-2H)(hydrazine)(H2O)]
  参考文献：
  名称：

  Preparation, Characterization, and Thermal Reactivity of Divalent Transition Metal Hydrazine Pyridine‐2,n‐dicarboxylates (n = 3, 4, 5, and 6)

  摘要：

  Metal hydrazine pyridine-2,n-dicarboxylate hydrates [M(L)N2H4.xH(2)O. where L = pyridine-2,n-dicarboxylate dianion and x = 1 -3] of cobalt, nickel. zinc, and cadmium with quinolinic (n = 3), isocinchomeronic (n = 5). and dipicolinic (n = 6), and nickel and cadmium with lutidinic (n = 4) acids have been prepared and characterized by analytical, spectroscopic, thermal. and x-ray powder diffraction studies. Electronic spectra and magnetic susceptibility measurements indicate that all the cobalt and nickel complexes are high-spin octahedral in nature. The IR data document the existence of bidentate bridging hydrazine [v(N-N) = 990-965cm(-1)] and tridentate pyridinedicarboxylates in all the complexes. On heating they lose their hydrated water molecules in one or two steps. The anhydrous compounds undergo exothermic dehydrazination between 200 and 330degreesC followed by decomposition of the organic component to give either the corresponding metal oxide or a mixture of metal oxide and metal carbonate as the final residue. The coordination of water has been substantiated by thermal analyses.

  DOI：

  10.1081/sim-120028306