[Mn^III(2-[2-(1H-(benzo[d]imidazol-2-yl)ethylimino)methyl]phenolate)2]ClO4 | 1401421-60-0

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: [Mn^III(2-[2-(1H-(benzo[d]imidazol-2-yl)ethylimino)methyl]phenolate)2]ClO4
• 英文别名: [Mn^III(sal-aebmz)2]ClO4
• CAS: 1401421-60-0
• 化学式: C₃₂H₂₈MnN₆O₂*ClO₄
• 分子量: 683.002
• InChiKey: PIHQTGZMUSQEAF-CQGBIQBTSA-K

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  2-(2-(1H-benzimidazol-2-yl)ethyliminomethyl)phenol 、 manganese(II)perchlorate hexahydrate 在 air 作用下， 以 甲醇 为溶剂， 反应 29.0h， 以65.2%的产率得到[Mn^III(2-[2-(1H-(benzo[d]imidazol-2-yl)ethylimino)methyl]phenolate)2]ClO4
  参考文献：
  名称：

  Mn(III) complexes of the monoprotic tridentate ONN donor 2-[2-(1H-(benzo[d]imidazol-2-yl)ethylimino)methyl]phenol as a functional mimic of haloperoxidase

  摘要：

  The reaction of Mn-II(ClO4)(2) with 2-[2-(1H-(benzo[d]imidazol-2-yl)ethylimino)methyl]phenol (Hsalaebmz, I) under aerobic conditions results in the formation of [Mn-III(sal-aebmz)(2)]center dot ClO4 (1). In the presence of triethylamine and using MnCl2 under aerobic conditions. I forms [Mn-III(sal-aebmz-H)(sal-aebmz)] (2). These complexes are characterised on the basis of elemental and electrochemical analyses, spectroscopic (IR and UV-Vis) data and thermogravimetric studies. Single crystal X-ray analysis of 2 shows that it is stabilized in the solid state through intermolecular hydrogen bonding between the NH groups of the two benzimidazole moieties after losing one of the hydrogen atoms: the coordination sites of the ligand are the imine nitrogen of the benzimidazole ring, the azomethine nitrogen and the deprotonated phenolic oxygen. Complex 2 catalyses the oxidative bromination of styrene by H2O2, yielding 1,2-dibromo-1-phenylethane, 1-phenylethane-1,2-diol and 2-bromo-1 -phenylethane-1-ol, acting as a functional mimic of haloperoxidases. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2012.07.095