| 1454321-56-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并咪唑类
• CAS: 1454321-56-2
• 化学式: C₆₃H₅₄Cl₅N₅O₅
• 分子量: 1138.42
• InChiKey: RPUKMFYQLGZCQU-UHFFFAOYSA-N

物化性质

• 密度：
  1.310±0.06 g/cm3(Temp: 20 °C; Press: 760 Torr)(predicted)

反应信息

• 作为反应物：
  描述：

  在 碘代三甲硅烷 作用下， 以 氯仿 为溶剂， 反应 23.0h， 以76%的产率得到5,11,17,23,29-Pentachloro-31,32,33,34,35-pentamethoxy-2,8,14,20,26-pentazahexacyclo[25.3.1.13,7.19,13.115,19.121,25]pentatriaconta-1(30),3,5,7(35),9,11,13(34),15,17,19(33),21(32),22,24,27(31),28-pentadecaene
  参考文献：
  名称：

  SYNTHESIS OF p-CHLOROAZACALIX[5]ARENE PENTAMETHYL ETHER: RING SIZE-DEPENDENT DEPROTECTION OF N-BENZYL GROUPS

  摘要：

  Syntheses of chlorinated azacalix[4]arene and azacalix[5]arene have been investigated. While the preparation of the former failed in the final N-debenzylation step, the latter was successfully obtained. The observed ring size-dependent deprotection was interpreted by steric effect.

  DOI：

  10.3987/com-12-s(n)48
• 作为产物：
  描述：

  在 R-(+)-1,1'-联萘-2,2'-双二苯膦 、 bis(dibenzylideneacetone)-palladium⁽⁰⁾ 、 sodium t-butanolate 作用下， 以 甲苯 为溶剂， 反应 30.0h， 以65%的产率得到
  参考文献：
  名称：

  SYNTHESIS OF p-CHLOROAZACALIX[5]ARENE PENTAMETHYL ETHER: RING SIZE-DEPENDENT DEPROTECTION OF N-BENZYL GROUPS

  摘要：

  Syntheses of chlorinated azacalix[4]arene and azacalix[5]arene have been investigated. While the preparation of the former failed in the final N-debenzylation step, the latter was successfully obtained. The observed ring size-dependent deprotection was interpreted by steric effect.

  DOI：

  10.3987/com-12-s(n)48