Ni(2-pyridinecarboxaldehyde thiosemicarbazone)2SO4 | 1020175-31-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: Ni(2-pyridinecarboxaldehyde thiosemicarbazone)2SO4
• CAS: 1020175-31-8
• 化学式: C₁₄H₁₆N₈NiO₄S₃
• 分子量: 515.22
• InChiKey: PJCKGILRVGDAAO-YFHINIJSSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  nickel(II) sulphate 、 (吡啶-2-基亚甲基氨基)硫脲 以 乙醇 为溶剂， 以69%的产率得到Ni(2-pyridinecarboxaldehyde thiosemicarbazone)2SO4
  参考文献：
  名称：

  Spectroscopic and biological approach of Ni(II) and Cu(II) complexes of 2-pyridinecarboxaldehyde thiosemicarbazone

  摘要：

  Ni(II) and Cu(II) complexes having the general composition [M(L)(2)X-2] [where L = 2-pyridinecarboxaldehyde thiosemicarbazone, M = Ni(II) and Cu(II), X=Cl-, NO3- and 1/2 SO42-] have been synthesized. All the metal complexes were characterized by elemental analysis, molar conductance, magnetic moment, mass, IR, EPR and electronic spectral studies. The magnetic moment measurements of the complexes indicate that all the complexes are of high-spin type. On the basis of spectral studies an octahedral geometry has been assigned for Ni(II) complexes whereas tetragonal geometry for Cu(II) except [Cu(L)(2)SO4] which posseses five coordinated geometry. The ligand and its metal complexes were screened against phytopathogenic fungi and bacteria in vitro. (c) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.saa.2007.05.033