2-(di-tert-butylphosphino)methyl-6-(diphenylphosphino)methylpyridine | 1415229-96-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 2-(di-tert-butylphosphino)methyl-6-(diphenylphosphino)methylpyridine
• 英文别名: Ditert-butyl-[[6-(diphenylphosphanylmethyl)pyridin-2-yl]methyl]phosphane；ditert-butyl-[[6-(diphenylphosphanylmethyl)pyridin-2-yl]methyl]phosphane
• CAS: 1415229-96-7
• 化学式: C₂₇H₃₅NP₂
• 分子量: 435.529
• InChiKey: SSNZUSKRTOQIEG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5
• 重原子数：
  30
• 可旋转键数：
  8
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.37
• 拓扑面积：
  12.9
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  2-(di-tert-butylphosphino)methyl-6-(diphenylphosphino)methylpyridine 在 0.5 wt% Na-Hg 作用下， 以 四氢呋喃 为溶剂， 反应 32.0h， 生成 [Mo(N₂)₂(2-(di-tert-butylphosphino)methyl-6-(diphenylphosphino)methylpyridine)]₂(μ-N₂)
  参考文献：
  名称：

  Synthesis and Catalytic Activity of Molybdenum–Dinitrogen Complexes Bearing Unsymmetric PNP-Type Pincer Ligands

  摘要：

  Novel dinitrogen-bridged dimolybdenum complexes bearing unsymmetric PNP-type pincer ligands are prepared and characterized by X-ray analysis. A molybdenum-dinitrogen complex bearing 2-(di-1-adamantylphosphino)methyl-6-(di-tert-butylphosphino)methylpyridine has been found to work as an effective catalyst toward the formation of ammonia from molecular dinitrogen under ambient conditions.

  DOI：

  10.1021/om301046t
• 作为产物：
  描述：

  二叔丁基氯化膦 、 2-(diphenylphosphino)methyl-6-methylpyridine 在 正丁基锂 作用下， 以 乙醚 、 正己烷 为溶剂， 反应 21.0h， 以89%的产率得到2-(di-tert-butylphosphino)methyl-6-(diphenylphosphino)methylpyridine
  参考文献：
  名称：

  Synthesis and Catalytic Activity of Molybdenum–Dinitrogen Complexes Bearing Unsymmetric PNP-Type Pincer Ligands

  摘要：

  Novel dinitrogen-bridged dimolybdenum complexes bearing unsymmetric PNP-type pincer ligands are prepared and characterized by X-ray analysis. A molybdenum-dinitrogen complex bearing 2-(di-1-adamantylphosphino)methyl-6-(di-tert-butylphosphino)methylpyridine has been found to work as an effective catalyst toward the formation of ammonia from molecular dinitrogen under ambient conditions.

  DOI：

  10.1021/om301046t

文献信息

• Synthesis and Catalytic Activity of Molybdenum–Dinitrogen Complexes Bearing Unsymmetric PNP-Type Pincer Ligands
  作者：Eriko Kinoshita、Kazuya Arashiba、Shogo Kuriyama、Yoshihiro Miyake、Ryuji Shimazaki、Haruyuki Nakanishi、Yoshiaki Nishibayashi

  DOI：10.1021/om301046t

  日期：2012.12.10

  Novel dinitrogen-bridged dimolybdenum complexes bearing unsymmetric PNP-type pincer ligands are prepared and characterized by X-ray analysis. A molybdenum-dinitrogen complex bearing 2-(di-1-adamantylphosphino)methyl-6-(di-tert-butylphosphino)methylpyridine has been found to work as an effective catalyst toward the formation of ammonia from molecular dinitrogen under ambient conditions.