(2,6-di-tert-butyl-4-methylphenoxo)(chloro)hydrido(trimethylamine)aluminium(III) | 147050-82-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (2,6-di-tert-butyl-4-methylphenoxo)(chloro)hydrido(trimethylamine)aluminium(III)
• CAS: 147050-82-6
• 化学式: C₁₈H₃₃AlClNO
• 分子量: 341.901
• InChiKey: IVRGXNBXTRTZQY-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  trimethylamine-chloroalane 、 2,6-二叔丁基-4-甲基苯酚 以 正戊烷 为溶剂， 以90%的产率得到(2,6-di-tert-butyl-4-methylphenoxo)(chloro)hydrido(trimethylamine)aluminium(III)
  参考文献：
  名称：

  Sterically crowded aryloxide compounds of aluminium: hydrides and homoleptic aryloxides

  摘要：

  Interaction of [AlH3(NMe3)] and [AlH2Cl(NMe3)] with HOR1 (R1 = C6H2But2-2,6-Me-4) allows for the isolation of [AlH2(OR1)(NMe3)] 1 and [Al(H)Cl(OR1)(NMe3)] 2 respectively. Compound 1 exists in both mono- and di-meric forms in the solid state. The reaction of 1 with NH2But results in ligand redistribution to give [AlH(OR1)2(NH2But)] 3. Similarly, multiple recrystallisation of 1 from Et2O allows for the isolation of [AlH(OR1)2(OEt2)] 4, while addition of HOR2 (R2 = C6H3Ph2-2,6) to 1 yields the mixed aryloxide complex [AlH(OR1)(OR2)(NMe3)] 5. Interaction of compound 1 with benzophenone results in the formation of the bridged dimer [{AlH(OR1)(mu-OCHPh2)}2] 6. The reaction of 3 molar equivalents of HOR1 with LiAlH4 yields, in addition to [{Li(OR1)(OEt2)}2], compound 4, which reacts further with H2O, HOR1 or NH2C6H2Cl3-2,4,6 to give [{Al(mu-OH)(OR1)2}2] 7, [Al(OR1)3] 8 or [Al(OR1)2(NHC6H2Cl3-2,4,6)] 13 respectively. Compounds 8 and 13 form stable Lewis acid-base complexes [Al(OR1)3L] [L = MeCN 9, pyridine (py) 10, O=PPh3 11 or O=C(C5H9)But-4 12] and [Al(OR1)2(NHC6H2Cl3-2,4,6)L] (L = Et2O 14, py 15 or 3,5-dimethylpyridine 16). The presence of a slow ligand exchange for compounds 9 and 12 was investigated by H-1 NMR spectroscopy. The molecular structures of 1, 3, 4, 8 and 12 have been confirmed by X-ray crystallography.

  DOI：

  10.1039/dt9930000441