2,3t-dichloro-acrylic acid amide | 3533-64-0

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 乙烯基卤化物
• 英文名称: 2,3t-dichloro-acrylic acid amide
• 英文别名: 2,3t-Dichlor-acrylsaeure-amid；2,3-dichloroacrylamide；(Z)-2,3-dichloroprop-2-enamide
• CAS: 3533-64-0
• 化学式: C₃H₃Cl₂NO
• 分子量: 139.969
• InChiKey: UWSDTNBDRVMTFU-UPHRSURJSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.8
• 重原子数：
  7
• 可旋转键数：
  1
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  43.1
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  (Z)-2,3-dichloro-acryloyl chloride 在 ammonium hydroxide 作用下， 以88%的产率得到2,3t-dichloro-acrylic acid amide
  参考文献：
  名称：

  Broad spectrum fungicidal diacylimide compositions

  摘要：

  该发明提供了广谱杀菌二酰亚胺组合物，其中包括具有以下结构的化合物：其中R和R'从1-5个碳原子的烷基、烯基、卤代烷基和卤代烯基中选择，可以是相同或不同的基团。该发明的这些组合物显示出优异的农业杀菌活性，特别对抗豆锈病、稻瘟病、番茄枯萎病和其他农业病原体。通常通过将适当的酰胺与酰卤反应来制备这些二酰亚胺化合物。如果必要，酰卤前体可通过与适当的卤化剂（如亚砜氯）反应从相应的酸制备。同样，给定的酰胺可以通过与氨反应从相应的酰卤中容易地制备。

  公开号：

  US04117163A1

文献信息

• Nematocide control diacylimide control diacylimide compositions
  申请人：GAF Corporation

  公开号：US04117162A1

  公开（公告）日：1978-09-26

  The invention provides nematocide control diacylimide compositions which include compounds having the formula: ##STR1## where R and R' are selected from alkyl, alkenyl, haloalkyl and haloalkenyl having from 1-5 carbon atoms, being the same or different groups. The compositions of this invention show excellent agricultural nematocidal activity, and particularly, the control of endoparasitic and ectoparasitic worms, such as the root knot nematocide, which exist in the soil at some stage of their life cycles. The diacylimide compounds generally are prepared by reacting a suitable amide with an acyl halide. The acyl halide precursor may be prepared, if necessary, from the corresponding acid by reaction with a suitable halogenating agent, such as thionyl chloride. Similarly, a given amide may be readily prepared, for example, from the corresponding acyl halide by reaction with ammonia.

  该发明提供了一种寄生虫控制二酰亚胺组合物，其中包括具有以下结构的化合物：##STR1## 其中R和R'从1-5个碳原子的烷基、烯基、卤代烷基和卤代烯基中选择，可以是相同或不同的基团。本发明的组合物表现出优异的农业寄生虫活性，特别是对内寄生虫和外寄生虫蠕虫的控制，例如存在于土壤中某个生命周期阶段的根结线虫。二酰亚胺化合物通常是通过将适当的酰胺与酰卤反应制备而成。如果需要，酰卤前体可以通过与适当的卤化剂（如氯化亚砜）反应从相应的酸制备而成。同样，给定的酰胺可以很容易地通过与氨反应从相应的酰卤制备而成。
• Broad spectrum fungicidal diacylimide compositions
  申请人：GAF Corporation

  公开号：US04117163A1

  公开（公告）日：1978-09-26

  The invention provides broad spectrum fungicidal diacylimide compositions which include compounds having the formula: ##STR1## where R and R' are selected from alkyl, alkenyl, haloalkyl and haloalkenyl having from 1-5 carbon atoms, being the same or different groups. The compositions of this invention show excellent agricultural fungicidal activity, particularly against bean rust, rice spot, tomato blight and other agricultural pathogens. The diacylimide compounds generally are prepared by reacting a suitable amide with an acyl halide. The acyl halide precursor may be prepared, if necessary, from the corresponding acid by reaction with a suitable halogenating agent, such as thionyl chloride. Similarly, a given amide may be readily prepared, for example, from the corresponding acyl halide by reaction with ammonia.

  该发明提供了广谱杀菌二酰亚胺组合物，其中包括具有以下结构的化合物：其中R和R'从1-5个碳原子的烷基、烯基、卤代烷基和卤代烯基中选择，可以是相同或不同的基团。该发明的这些组合物显示出优异的农业杀菌活性，特别对抗豆锈病、稻瘟病、番茄枯萎病和其他农业病原体。通常通过将适当的酰胺与酰卤反应来制备这些二酰亚胺化合物。如果必要，酰卤前体可通过与适当的卤化剂（如亚砜氯）反应从相应的酸制备。同样，给定的酰胺可以通过与氨反应从相应的酰卤中容易地制备。
• Kurtz et al., Journal of Organic Chemistry, 1965, vol. 30, p. 3141,3146
  作者：Kurtz et al.

  DOI：——

  日期：——
• Aquatic herbicidal diacylimide compositions
  申请人：GAF Corporation

  公开号：US04154594A1

  公开（公告）日：1979-05-15

  The invention provides broad spectrum herbicidal diacylimide compositions which include compounds having the formula: ##STR1## where R and R' are selected from alkyl, alkenyl, haloalkyl and haloalkenyl having from 1-5 carbon atoms, being the same or different groups. The compositions of this invention show excellent agricultural herbicidal activity, particularly against foxtail millet, Japanese millet, crabgrass and pigweed, and aquatic herbicidal activity against lower and higher submerged aquatic plants. The diacylimide compounds generally are prepared by reacting a suitable amide with an acyl halide. The acyl halide precursor may be prepared, if necessary, from the corresponding acid by reaction with a suitable halogenating agent, such as thionyl chloride. Similarly, a given amide may be readily prepared, for example, from the corresponding acyl halide by reaction with ammonia.

  该发明提供了广谱除草二酰亚胺组合物，其包括具有以下结构的化合物：##STR1##其中R和R'选自具有1-5个碳原子的烷基，烯基，卤代烷基和卤代烯基，可以是相同或不同的基团。该发明的组合物显示出优秀的农业除草活性，特别对狐尾稗、日本稗、狗尾草和苋菜具有活性，并且对低水生和高水生植物具有水生除草活性。通常通过将适当的酰胺与酰卤反应来制备二酰亚胺化合物。如果必要，酰卤前体可以通过与适当的卤化试剂（如氯化硫酰）反应从相应的酸制备。同样，给定的酰胺可以通过与氨反应从相应的酰卤轻松制备。