di(thiocyanato-N)tetrakis(2-(3'-tolyl)-benzothiazole)nickel(II) | 590369-35-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: di(thiocyanato-N)tetrakis(2-(3'-tolyl)-benzothiazole)nickel(II)
• CAS: 590369-35-0
• 化学式: C₅₈H₄₄N₆NiS₆
• 分子量: 1076.11
• InChiKey: DYTRYZYENGWNGA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2-(3-甲基苯基)-1,3-苯并噻唑 、 nickel(II) thiocyanate 以 乙醇 为溶剂， 以45%的产率得到di(thiocyanato-N)tetrakis(2-(3'-tolyl)-benzothiazole)nickel(II)
  参考文献：
  名称：

  Metal Thiocyanato Complexes: Synthesis, Magnetic, and Spectral Studies of Some Mixed‐Ligand Thiocyanato Complexes of Nickel(II) Involving Benzothiazole and Benzimidazole Derivatives

  摘要：

  A new series of mixed-ligand thiocyanato complexes of nickel(II) of the compositions [Ni(NCS)(2)(L)(4)], where L = 2-mercaptobenzothiazole (2-MBZT), 2-(2'-hydroxyphenyl)-benzothiazole (2'-HPBZT), 2-(2'-tolyl)benzothiazole (2'-TOBZT), 2-(3'-tolyl)benzothiazole (3'-TOBZT), [Ni(NCS)(2)(2-AMBZT)(2)] and [Ni(NCS)(2)(BBZLY)(H2O)(2)], where 2-AMBZT = 2-aminobenzothiazole and BBZLPY = 2,6-bis(benzimidazole-2'-yl)pyridine, has been synthesized by the interaction of nickel(II) thiocyanate with the respective ligands. The compounds so obtained were characterized by analytical data, molar conductances, magnetic measurements, infrared and electronic spectral studies. Suitable octahedral structures have been suggested for these complexes.

  DOI：

  10.1081/sim-120019992