(4-(3,3,4,4,5,5-hexafluoro-2-(2-methyl-5-phenylthiophen-3-yl)cyclopent-1-enyl)-5-methylthiophen-2-yl)trimethylsilane | 1263304-44-4

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: (4-(3,3,4,4,5,5-hexafluoro-2-(2-methyl-5-phenylthiophen-3-yl)cyclopent-1-enyl)-5-methylthiophen-2-yl)trimethylsilane
• CAS: 1263304-44-4
• 化学式: C₂₄H₂₂F₆S₂Si
• 分子量: 516.647
• InChiKey: DUEVDFFLMUJIFX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.47
• 重原子数：
  33.0
• 可旋转键数：
  4.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为产物：
  描述：

  3-bromo-2-methyl-5-trimethylsilylthiophene 、 1-[2-methyl-5-phenyl-3-thienyl]heptafluorocyclopentene 在 正丁基锂 作用下， 以 乙醚 、 正己烷 为溶剂， 反应 3.67h， 生成 (4-(3,3,4,4,5,5-hexafluoro-2-(2-methyl-5-phenylthiophen-3-yl)cyclopent-1-enyl)-5-methylthiophen-2-yl)trimethylsilane
  参考文献：
  名称：

  Multifunctional photo- and thermo-responsive copolymer nanoparticles

  摘要：

  A novel amphiphilic photochromic copolymer P1-o consisting of a hydrophilic poly(N-isopropylacrylamide) backbone and thermally irreversible photochromic and hydrophobic 1,2-dithienylethene derivative pendants was designed, synthesized and used to fabricate self-assembled copolymer nanoparticles in an aqueous condition. The hydrodynamic diameters of the multifunctional copolymer P1-o nanoparticles reversibly switched between two stable states with two stimuli: light and temperature in an aqueous suspension.Graphical abstract:(C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.dyepig.2010.03.013