Pd(N-butyl-pyridine-2-carbaldimine)(4,5-disulfanyl-1,3-dithiol-2-thionate(2-)) | 335080-07-4

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: Pd(N-butyl-pyridine-2-carbaldimine)(4,5-disulfanyl-1,3-dithiol-2-thionate(2-))
• 英文别名: Pd(Bu-pya)(C3S5)
• CAS: 335080-07-4
• 化学式: C₁₃H₁₄N₂PdS₅
• 分子量: 465.018
• InChiKey: VKFXSPOLQXSRDE-OTBYXNOXSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  Pd(N-butyl-pyridine-2-carbaldimine)(4,5-disulfanyl-1,3-dithiol-2-thionate(2-)) 、 碘 以 氯仿 、 N,N-二甲基甲酰胺 为溶剂， 以59%的产率得到[Pd(N-butyl-pyridine-2-carbaldimine)(4,5-disulfanyl-1,3-dithiol-2-thionate(2-))](I1.8)
  参考文献：
  名称：

  Preparation of Pt(II) and Pd(II) complexes coordinated with both a diimine ligand and a sulfur-rich dithiolate ligand and electrical conductivities of their oxidized species and X-ray crystal structure of Pd(N-butyl-pyridine-2-carbaldimine)(C3S5)

  摘要：

  Pt(L)(C8H4S8) [L = 2,2 ' -bipyridine (bpy) and N-butyl-pyridine-2-carbaldimine (Bu-pya): C8H4S82- = 2-{(4,5-ethylenedithio)-1,3-dithiol-2-ylidene}-1,3-dithiol-4,5-dithionate(2-)]. Pd(Bu-pya)(C8H4S8), and Pd(Bu-pya)(C3S8) [C10-C6S82- = 2-{bis(dodecylthio)-1,3-dithiol-2-ylidene}-1,3-dithiol-4,5-dithiolate(2-)]. Pd(Bu-pya)(C8H4S8), and Pd(Bu-pya)(C3S8) [C3S82- = 4,5-disulfanyl-1,3-dithiol-2-thionate(2-)] were prepared. They showed intense electronic absorption bands due to an intramolecular mixed ligand-to-ligand charge transfer transition which is sensitive to a solvent. They exhibit oxidation potentials of -0.18 and +0.35 V (versus Ag/Ag-) with oxidation of the dithiolate ligand. They were oxidized by iodine or TCNQ (7,7,8,8-tetracyano-p-quinodimethane) to afford [Pt(L)(C8H4S8)](I-3)(y)(x = 0.9-1.0). [Pt(L)(C8H4S8)](TCNQ)(x) (y = 0.6-0.8) (L = bpy), Bu-pya and C10-C6S8) and [Pd(Bu-pya)(C8H4S8)I-.(5.1) and [Pd(Bu-pya)(C8H4S8)](TCNQ)(0.4). The [Pt(L)(C8H4S8)]-oxidized complexes behave as electrical conductors with conductivities of 1.4 x 10(-5)-10(-3) S cm(-1) measured for compacted pellets at room temperature, while the [Pd(Bu-pya)(C8H4S8)]-oxidized species exhibit conductivities of (1.4-3.2) x 10(-3) S cm(-1). The X-ray crystal structure of Pd(Bu-pya)(C3S8) revealed a one-dimensional array of the molecules constructed with some sulfur-sulfur non-bonded contacts. (C) 2000 Elesevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(00)00274-7
• 作为产物：
  描述：

  [(N-(n-butyl)-N-(pyridin-2-ylmethylene)amine)dichloropalladium(II)] 、 bis(tetra-n-butylammonium) bis(1,3-dithiole-2-thione-4,5-dithiolato)zinc(II) 以 二氯甲烷 为溶剂， 以22%的产率得到Pd(N-butyl-pyridine-2-carbaldimine)(4,5-disulfanyl-1,3-dithiol-2-thionate(2-))
  参考文献：
  名称：

  Preparation of Pt(II) and Pd(II) complexes coordinated with both a diimine ligand and a sulfur-rich dithiolate ligand and electrical conductivities of their oxidized species and X-ray crystal structure of Pd(N-butyl-pyridine-2-carbaldimine)(C3S5)

  摘要：

  Pt(L)(C8H4S8) [L = 2,2 ' -bipyridine (bpy) and N-butyl-pyridine-2-carbaldimine (Bu-pya): C8H4S82- = 2-{(4,5-ethylenedithio)-1,3-dithiol-2-ylidene}-1,3-dithiol-4,5-dithionate(2-)]. Pd(Bu-pya)(C8H4S8), and Pd(Bu-pya)(C3S8) [C10-C6S82- = 2-{bis(dodecylthio)-1,3-dithiol-2-ylidene}-1,3-dithiol-4,5-dithiolate(2-)]. Pd(Bu-pya)(C8H4S8), and Pd(Bu-pya)(C3S8) [C3S82- = 4,5-disulfanyl-1,3-dithiol-2-thionate(2-)] were prepared. They showed intense electronic absorption bands due to an intramolecular mixed ligand-to-ligand charge transfer transition which is sensitive to a solvent. They exhibit oxidation potentials of -0.18 and +0.35 V (versus Ag/Ag-) with oxidation of the dithiolate ligand. They were oxidized by iodine or TCNQ (7,7,8,8-tetracyano-p-quinodimethane) to afford [Pt(L)(C8H4S8)](I-3)(y)(x = 0.9-1.0). [Pt(L)(C8H4S8)](TCNQ)(x) (y = 0.6-0.8) (L = bpy), Bu-pya and C10-C6S8) and [Pd(Bu-pya)(C8H4S8)I-.(5.1) and [Pd(Bu-pya)(C8H4S8)](TCNQ)(0.4). The [Pt(L)(C8H4S8)]-oxidized complexes behave as electrical conductors with conductivities of 1.4 x 10(-5)-10(-3) S cm(-1) measured for compacted pellets at room temperature, while the [Pd(Bu-pya)(C8H4S8)]-oxidized species exhibit conductivities of (1.4-3.2) x 10(-3) S cm(-1). The X-ray crystal structure of Pd(Bu-pya)(C3S8) revealed a one-dimensional array of the molecules constructed with some sulfur-sulfur non-bonded contacts. (C) 2000 Elesevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(00)00274-7