4-正癸基硫酚 | 4527-50-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯硫酚类
• 中文名称: 4-正癸基硫酚
• 英文名称: 4-Decyl-thiophenol
• 英文别名: 4-n-Decyl-thiophenol；4-n-Decylbenzolthiol；4-Decylbenzenethiol
• CAS: 4527-50-8
• 化学式: C₁₆H₂₆S
• 分子量: 250.448
• InChiKey: TWYYEGXSFYSRNP-UHFFFAOYSA-N

物化性质

• 沸点：
  170-173 °C(Press: 3 Torr)
• 密度：
  0.9303 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  6.9
• 重原子数：
  17
• 可旋转键数：
  9
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.62
• 拓扑面积：
  1
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  4-正庚基苯甲醛 、 4-正癸基硫酚 在 叔丁基过氧化氢 、 Cl₄Fe^(1-)*C₉H₇N₃O₂*H⁽¹⁺⁾ 作用下， 以 neat (no solvent) 为溶剂， 反应 1.0h， 以64%的产率得到S-decyl octanethioate
  参考文献：
  名称：

  Tunable Aryl Imidazolium Recyclable Ionic Liquid with Dual Brønsted–Lewis Acid as Green Catalyst for Friedel–Crafts Acylation and Thioesterification

  摘要：

  独特可调节的芳基咪唑离子液体成功地催化了密封管中的Friedel-Crafts酰化和硫酯化反应。这些反应可以以高原子经济性形成C−C键和C−S键。离子液体表现出高活性，催化了必要的反应，产率良好至优良，同时保持其催化活性以进行循环利用。

  DOI：

  10.3390/molecules25020352
• 作为产物：
  描述：

  p-n-Decylbenzolsulfonylchlorid 以4%的产率得到
  参考文献：
  名称：

  NEUBERT M. E.; LASKOS S. J.; GRIFFITH R. F.; STAHL M. E.; MAURER L. J., MOL. CRYST. AND LIQUID CRYST., 1979, 54, NO 3-4, 221-236

  摘要：

  DOI：

文献信息

• Organic Semiconductor Material
  申请人：Miyata Yasuo

  公开号：US20110087034A1

  公开（公告）日：2011-04-14

  A dihydroindacene compound represented by the following formula (1): wherein R 1 is identical or different from each other, and each denotes a hydrogen atom, alkyl which may be substituted, alkenyl which may be substituted, alkynyl which may be substituted, alkoxy which may be substituted, alkylthio which may be substituted, aryl which may be substituted, aryloxy which may be substituted, or the like; R 2 to R 5 are identical or different from each other, and each denote a hydrogen atom, alkyl which may be substituted, alkenyl which may be substituted, or the like; p is 0, 1, or 2; and ring structures A and B are identical or different from each other, and each denote a benzene ring which may be substituted, a thiophene ring which may be substituted, or the like.

  一种二氢吲哚嗪化合物，其由以下式（1）表示：其中R1彼此相同或不同，各自表示氢原子、可被取代的烷基、可被取代的烯基、可被取代的炔基、可被取代的烷氧基、可被取代的烷硫基、可被取代的芳基、可被取代的芳氧基等；R2至R5彼此相同或不同，各自表示氢原子、可被取代的烷基、可被取代的烯基等；p为0、1或2；环结构A和B彼此相同或不同，各自表示可被取代的苯环、可被取代的噻吩环等。
• PROCESS FOR PRODUCING OLEFIN OLIGOMER
  申请人：NABIKA Masaaki

  公开号：US20070027350A1

  公开（公告）日：2007-02-01

  A process for producing an olefin oligomer, which comprises the steps of (1) contacting a transition metal compound with a compound represented by the formula, R 1 R 2 A-G-AR 3 R 4 , to produce a contact product (i), (2) contacting an alumoxane compound with an organoaluminum compound to produce a contact product (ii), and (3) contacting the contact product (i), the contact product (ii), and an olefin with one another, wherein A is a nitrogen atom, a phosphorus atom, an arsenic atom or an antimony atom; G is a divalent group; and R 1 , R 2 , R 3 and R 4 are independently of one another a hydrocarbyl group, a halogenated hydrocarbyl group, an oxygen-containing hydrocarbyl group, a sulfur-containing hydrocarbyl group, a selenium-containing hydrocarbyl group, or a tellurium-containing hydrocarbyl group.

  一种生产烯烃寡聚物的方法，包括以下步骤：(1)将过渡金属化合物与由公式R1R2A-G-AR3R4表示的化合物接触，以产生接触产物(i)；(2)将铝氧烷化合物与有机铝化合物接触，以产生接触产物(ii)；(3)将接触产物(i)、接触产物(ii)和烯烃相互接触，其中A为氮原子、磷原子、砷原子或锑原子；G为二价基团；R1、R2、R3和R4分别独立地为烃基、卤代烃基、含氧烃基、含硫烃基、含硒烃基或含碲烃基。
• Olefin polymerization catalyst and process for producing olefin polymer
  申请人：Sumitomo Chemical Company, Limited

  公开号：EP1081167A1

  公开（公告）日：2001-03-07

  An olefin polymerization catalyst prepared by contacting a specified transition metal compound(A) having a cyclopentadiene type anion skeletons in its molecule with a modified aluminum oxy compound (B) obtained by reacting an aluminum oxy compound(B1) with a compound having a hydroxyl group(B2), and a process for producing an olefin polymer using the olefin polymerization catalyst.

  一种烯烃聚合催化剂，其制备方法是将分子中含有环戊二烯型阴离子骨架的特定过渡金属化合物（A）与铝氧化合物（B1）和具有羟基的化合物（B2）反应得到的改性铝氧化合物（B）接触，以及使用该烯烃聚合催化剂生产烯烃聚合物的工艺。
• ORGANIC SEMICONDUCTOR MATERIAL
  申请人：Sumitomo Chemical Company, Limited

  公开号：EP2248818A1

  公开（公告）日：2010-11-10

  A dihydroindacene compound represented by the following formula (1): wherein R1 is identical or different from each other, and each denotes a hydrogen atom, alkyl which may be substituted, alkenyl which may be substituted, alkynyl which may be substituted, alkoxy which may be substituted, alkylthio which may be substituted, aryl which may be substituted, aryloxy which may be substituted, or the like; R2 to R5 are identical or different from each other, and each denote a hydrogen atom, alkyl which may be substituted, alkenyl which may be substituted, or the like; p is 0, 1, or 2; and ring structures A and B are identical or different from each other, and each denote a benzene ring which may be substituted, a thiophene ring which may be substituted, or the like.

  下式(1)代表的二氢茚化合物： 其中 R1 彼此相同或不同，各自表示氢原子、可被取代的烷基、可被取代的烯基、可被取代的炔基、可被取代的烷氧基、可被取代的烷硫基、可被取代的芳基、可被取代的芳氧基或类似物；R2 至 R5 彼此相同或不同，各自表示氢原子、可被取代的烷基、可被取代的烯基或类似物； p 为 0、1 或 2；以及 环结构 A 和 B 彼此相同或不同，各自表示可被取代的苯环、可被取代的噻吩环或类似环。
• Catalyst component and catalyst for addition polymerization, and process for producing addition polymer
  申请人：——

  公开号：US20040186009A1

  公开（公告）日：2004-09-23

  A catlyst component obtained by a process comprising contacting (a), (b) and (c) described below, a catalyst for addition polymerization using the catalyst component, and a process for producing an addition polymer with the catalyst for addition polymerization: (a) a compound represented by the chemical formula, BiL 1 r , (b) a compound represented by the chemical formula, R 1 s-1 T 1 H, and (c) a compound represented by the chemical formula, R 2 t-2 T 2 H 2 , wherein r is a numeral corresponding to a valence of Bi; L 1 is a hydrogen atom, a halogen atom, a hydrocarbon group or a hydrocarbon oxy group; respective T 1 and T 2 independently represents a non-metallic atom of Group 15 or 16 of the periodic table; s represents a numeral corresponding to a valence of T 1 ; t represents a numeral corresponding to a valence of T 2 ; R 1 is an electron-withdrawing group or an electron-withdrawing group-containing group; and R 2 represents a hydrocarbon group.

  一种通过以下工艺获得的催化剂组分，该工艺包括将下述(a)、(b)和(c)接触，使用该催化剂组分的加成聚合催化剂，以及使用该加成聚合催化剂生产加成聚合物的工艺： (a) 化学式为 BiL 1 r , (b) 化学式为 R 1 s-1 T 1 H，以及 (c) 化学式为 R 2 t-2 T 2 H 2 , 其中 r 是与 Bi 的化合价相对应的数字； L 1 是氢原子、卤素原子、烃基或烃氧基；各自的 T 1 和 T 2 分别代表元素周期表中第 15 或 16 族的非金属原子；s 代表与 T 1 代表与 T 1 的化合价相对应的数字； t 代表与 T 2 的化合价相对应的数字。 2 ; R 1 是一个吸电子基团或一个含电子吸附基团；以及 R 2 代表烃基。