nickel 2,9,16,23-tetra-{5-(4-nitrophenyl)-[1,3,4]-oxadiazol-2-yl}phthalocyanine | 1261064-83-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: nickel 2,9,16,23-tetra-{5-(4-nitrophenyl)-[1,3,4]-oxadiazol-2-yl}phthalocyanine
• CAS: 1261064-83-8
• 化学式: C₆₄H₂₈N₂₀NiO₁₂
• 分子量: 1327.74
• InChiKey: JHNRHVHNAIRHIA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  nickel(II)-4,4',4'',4'''-phthalocyanine tetracarboxylic acid 、 4-硝基苯酰肼 在 四磷十氧化物 作用下， 反应 21.0h， 以80%的产率得到nickel 2,9,16,23-tetra-{5-(4-nitrophenyl)-[1,3,4]-oxadiazol-2-yl}phthalocyanine
  参考文献：
  名称：

  Decorating nickel phthalocyanine periphery by aryl-,,-oxadiazole pendants: synthesis, characterization, and conductivity studies

  摘要：

  We have decorated nickel phthalocyanine (NiPc) periphery by four different aryl-[1,3,4]-oxadiazole pendants. Introduction of aryl-[1,3,4]-oxadiazole pendants into the NiPc core results in improved thermal stability, fine-tuning of the position of the Q-band with decrease in band gap, indicating effective electronic communication between the two different ring systems with NiPc core. The magnitude of DC electrical conductivity for aryl-[1,3,4]-oxadiazole-substituted NiPcs 3a-3d is found to be 105 times higher than the parent NiPc (1). The temperature-dependent DC conductivity studies reveal semiconducting nature of the newly synthesized NiPc compounds with significant decrease in thermal activation energy (E) compared to parent NiPc.

  DOI：

  10.1080/00958972.2010.529902