| 774504-74-4

• 分子结构分类: 有机化合物
• CAS: 774504-74-4
• 化学式: C₁₆H₁₃MnNO₃
• 分子量: 322.222
• InChiKey: GYSTUEQHOQHCTH-VNKRLIBXSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  水杨醛 、 DL-苯丙氨酸 、 manganese (II) acetate tetrahydrate 在 sodium hydroxide 作用下， 以 乙醇 为溶剂， 生成
  参考文献：
  名称：

  Amino acid Schiff base complex catalyst for effective oxidation of olefins with molecular oxygen

  摘要：

  The amino acid Schiff base manganese complex (Sal-Phe-Mn) was prepared with L-phenylalanine, salicylaldehyde and Mn(OAc)(2). 4H(2)O. The ligand and the complex were characterized by the infrared spectra, small area X-ray photoelectron spectroscopy,:and ICP-AES. in the presence of the manganese complex, cyclohexene was effectively oxidized by molecular oxygen without reductant. The major products of the reaction were 2-cyclohexen-1-ol (-OH), 2-cyclohexen-1-one (C=O) and 2-cyclohexen-1-hydroperoxide (-OOH), which was different with typical oxidation of cyclohexene. The influence of reaction temperature and additive for oxidation had been studied. The selectivity of 2-cyclohexen-1-hydroperoxide varied with reaction time and different additives. The mechanism of cyclohexene oxidation had also been discussed. (C) 1999 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s1381-1169(99)00143-0