2,4,6-tris(2-hydroxy-4-(1-methoxycarbonylethoxy)phenyl)-1,3,5-triazine | 250264-23-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,4,6-tris(2-hydroxy-4-(1-methoxycarbonylethoxy)phenyl)-1,3,5-triazine
• 英文别名: methyl 2-[4-[4,6-bis[2-hydroxy-4-(1-methoxy-1-oxopropan-2-yl)oxyphenyl]-1,3,5-triazin-2-yl]-3-hydroxyphenoxy]propanoate
• CAS: 250264-23-4
• 化学式: C₃₃H₃₃N₃O₁₂
• 分子量: 663.638
• InChiKey: CQNKTMGYONATEK-UHFFFAOYSA-N

物化性质

• 沸点：
  845.4±75.0 °C(Predicted)
• 密度：
  1.347±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.8
• 重原子数：
  48
• 可旋转键数：
  15
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.27
• 拓扑面积：
  206
• 氢给体数：
  3
• 氢受体数：
  15

反应信息

• 作为反应物：
  描述：

  2,4,6-tris(2-hydroxy-4-(1-methoxycarbonylethoxy)phenyl)-1,3,5-triazine 、 对甲苯磺酸一水合物 、 辛醇 、 甲醇 在 水 、 silica gel 作用下， 以 邻二甲苯 为溶剂， 反应 10.0h， 生成 tinuvin 477
  参考文献：
  名称：

  Triresorcinyl triazines

  摘要：

  该式中，Z、Z'和Z''独立于彼此，均为式II的基团，R7为式III、IV或V的基团，其中n为1或2；R4、R5和R6独立于彼此，均为C1-C18烷基、C5-C12环烷基、C2-C18烯基、苯基、C7-C11苯基烷基、C7-C11烷基苯基、被苯基、OH、C1-C18烷氧基、C5-C12环烷氧基、C3-C18烯氧基、COOH、COOR11、O—COR12、CONH2、CONHR13、CONR13NR14、CN、NH2、NHR13、NR13R14、NHCOR12、C6-C15双环烷基、C6-C16双环烷氧基、C6-C16双环烯基氧基或C6-C15三环烷氧基取代的C1-C18烷基；被OH、C1-C4烷基、C2-C6烯基或O—COR12取代的C5-C12环烷基；或COR15；CO—X—R11；或SO2—R16；或C3-C50烷基被O中断和/或取代的OH、苯氧基或C7-C18烷基苯氧基；或R5和R6一起构成环结构；X和Y独立于彼此，均为O、NH、NR13或S；其他符号如权利要求1所定义，对有机材料光、氧和/或热损伤的稳定剂有效。

  公开号：

  US06346619B1
• 作为产物：
  描述：

  2-氯丙酸甲酯 、 2,4,6-三(2,4-二羟基苯基)-1,3,5-三嗪 生成 2,4,6-tris(2-hydroxy-4-(1-methoxycarbonylethoxy)phenyl)-1,3,5-triazine
  参考文献：
  名称：

  Triresorcinyl triazines

  摘要：

  式中的化合物，其中Z，Z'和Z''彼此独立地是式II的一个基团，而R7是式III，IV或V的一个基团，其中n为1或2；R4，R5和R6彼此独立地是C1-C18烷基；C5-C12环烷基；C2-C18烯基；苯基；C7-C11苯基烷基；C7-C11烷基苯基；被苯基，OH，C1-C18烷氧基，C5-C12环烷氧基，C3-C18烯氧基，COOH，COOR11，O—COR12，CONH2，CONHR13，CONR13NR14，CN，NH2，NHR13，NR13R14，NHCOR12，C6-C15双环烷基，C6-C16双环烷氧基，C6-C16双环烯基氧基或C6-C15三环烷氧基取代的C1-C18烷基；被OH，C1-C4烷基，C2-C6烯基或O—COR12取代的C5-C12环烷基；或COR15；CO—X—R11；或SO2—R16；或被O打断和/或取代的C3-C50烷基，OH，苯氧基或C7-C18烷基苯氧基；或R5和R6一起形成一个环结构；X和Y彼此独立地是O，NH，NR13或S；其他符号如权利要求1所定义的对有机材料对抗光，氧和/或热的破坏效应具有稳定作用。

  公开号：

  US06346619B1

文献信息

• Trisresorcinyltriazines
  申请人：——

  公开号：US20020086922A1

  公开（公告）日：2002-07-04

  Compounds of the formula 1 in which Z, Z′ and Z″ independently of one another are a group of the formula II 2 (II) and R 7 is a radical of the formula III, IV or V 3 in which n is 1 or 2; R 4 , R 5 and R 6 independently of one another are C 1 -C 18 alkyl; C 5 -C 12 cycloalkyl; C 2 -C 18 alkenyl; phenyl; C 7 -C 11 phenylalkyl; C 7 -C 11 alkylphenyl; C 1 -C 18 alkyl substituted by phenyl, OH, C 1 -C 18 alkoxy, C 5 -C 12 cycloalkoxy, C 3 -C 18 alkenyloxy, COOH, COOR 11 , O—COR 12 , CONH 2 , CONHR 13 , CONR 13 NR 14 , CN, NH 2 , NHR 13 , NR 13 R 14 , NHCOR 12 , C 6 -C 15 bicycloalkyl, C 6 -C 16 bicycloalkyl-alkoxy, C 6 -C 16 bicycloalkenyl-alkoxy or C 6 -C 15 tricycloalkoxy; C 5 -C 12 cycloalkyl substituted by OH, C 1 -C 4 alkyl, C 2 -C 6 alkenyl or O—COR 12 ; or COR 15 ; CO—X—R 11 ; or SO 2 —R 16 ; or C 3 -C 50 alkyl interrupted by O and/or substituted by OH, phenoxy or C 7 -C 18 alkylphenoxy; or R 5 and R 6 together form a ring structure; X and Y independently of one another are O, NH, NR 13 or S; and the other symbols are as defined in claim 1 are effective as stabilizers for organic material against the damaging effect of light, oxygen and/or heat.

  式1的化合物中，其中Z、Z'和Z''互相独立，是式II2(II)的基团，而R7是式III、IV或V3的基团，其中n为1或2；R4、R5和R6互相独立，是C1-C18烷基、C5-C12环烷基、C2-C18烯基、苯基、C7-C11苯基烷基、C7-C11烷基苯基、被苯基、OH、C1-C18烷氧基、C5-C12环烷氧基、C3-C18烯氧基、COOH、COOR11、O—COR12、CONH2、CONHR13、CONR13NR14、CN、NH2、NHR13、NR13R14、NHCOR12、C6-C15双环烷基、C6-C16双环烷氧基、C6-C16双环烯基氧基或C6-C15三环氧基取代的C1-C18烷基；被OH、C1-C4烷基、C2-C6烯基或O—COR12取代的C5-C12环烷基；或COR15；CO—X—R11；或SO2—R16；或C3-C50烷基被O打断和/或被OH、苯氧基或C7-C18烷基苯氧基取代；或R5和R6一起形成一个环结构；X和Y互相独立，是O、NH、NR13或S；其它符号如权利要求1所定义的，在有机材料中对抗光、氧和/或热的损害具有有效的稳定剂作用。
• Resin composition, cured film, method for producing cured film, and display device
  申请人：Toray Industries, Inc.

  公开号：US10858509B2

  公开（公告）日：2020-12-08

  Provided is a resin composition which contains a UV absorbent having high solubility in solvents, and imparts superior UV-cut performance and transparency, and good weather resistance, even when being formed as a thin film. The resin composition contains a UV absorbent (a) and a resin (b), wherein the UV absorbent (a) contains at least two compounds, i.e., a compound (a-1) having a global absorption maximum at less than 340 nm, and a compound (a-2) having a global absorption maximum at 340-380 nm, and the total content of (a-1) and (a-2) is 10-30 mass % of the total solid content.

  本发明提供了一种树脂组合物，该树脂组合物含有在溶剂中具有高溶解度的紫外线吸收剂，即使在形成薄膜时也具有优异的紫外线切割性能和透明度，以及良好的耐候性。该树脂组合物含有紫外线吸收剂（a）和树脂（b），其中紫外线吸收剂（a）至少含有两种化合物，即在 340 纳米以下具有全局吸收最大值的化合物（a-1）和在 340-380 纳米具有全局吸收最大值的化合物（a-2），且（a-1）和（a-2）的总含量占总固体含量的 10-30 质量%。
• Highly compatible hydroxyphenyltriazine UV-absorbers
  申请人：Lazzari Dario

  公开号：US20070161726A1

  公开（公告）日：2007-07-12

  The present invention relates to highly compatible hydroxyphenyltriazine UV-absorbers and to their use in protecting plants in green houses and the protection of foodstuffs, beverages, pharmaceuticals, cosmetics, personal care products, shampoos and the like from the deleterious effects of ultraviolet radiation. It has been found that certain highly compatible tris-aryl-s-triazines are especially effective towards this end when incorporated in the containers or films in which such materials are stored.
• ULTRAVIOLET LIGHT ABSORBING OPTICAL ELEMENTS AND COMPOSITIONS AND METHODS FOR MANUFACTURE
  申请人：Chen Fang

  公开号：US20100041787A1

  公开（公告）日：2010-02-18

  The present invention relates to a UV absorbing optical element comprising a polymer optical element substrate, and a UV light absorbing amount of a tris-aryltriazine-based UV absorber incorporated in said substrate. The present invention also provides a method for forming a UV absorbing optical element.
• RESIN SUBSTRATE PROVIDED WITH COATING LAYER
  申请人：Shibuya Takashi

  公开号：US20100227161A1

  公开（公告）日：2010-09-09

  To provide a resin substrate provided with a coating layer having excellent weather resistance and thereby capable of maintaining properties of the resin such as transparency and fracture resistance over a long period of time. A resin substrate provided with a coating layer, which comprises a substrate made of a resin containing an aromatic ring and a coating layer containing an acrylic polymer having an acid value of at most 1 mg KOH/g, a glass transition point of from 60° C. to 150° C. and a mass average molecular weight of from 90,000 to 1,000,000, and an ultraviolet light absorbing component selected from a polymer having ultraviolet light absorbing groups and an ultraviolet light absorber, having an average of absorption coefficients of from 3.5 g/(mg·cm) to 100 g/(mg·cm) to light in a wavelength region of from 350 nm to 380 nm, formed on at least one surface of the substrate.