| 176913-53-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• CAS: 176913-53-4
• 化学式: C₃₉H₂₇Cl₂FeN₃O₆S₂*ClO₃S
• 分子量: 940.062
• InChiKey: IXAYCAHXGFPHMG-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  吖啶 、 Ferric chlorosulphate 以 乙腈 为溶剂， 以65%的产率得到
  参考文献：
  名称：

  Synthesis and Physico-Chemical Studies on the Coordinating Behaviour of Chlorosulphate Ion in Metaltris(chlorosulphates), M(SO₃Cl)₃[M = Cr, Mn, Fe], and Their Complexes

  摘要：

  The solvolytic reaction of chromium(III) chloride, manganese(III) acetate and iron(III) chloride in chlrosulphuric acid afforded the formation of CR(SO3Cl)(3), Mn(SO3Cl)(3) and Fe(SO3Cl)(3) respectively, where the chlorosulphuric acid acts both as medium of reaction as well as chlorosulphonating agent. These compounds are hygroscopic and dissolve in most non-polar solvents. The IR spectra of these compounds suggest that the SO3Cl- group is covalently bonded to the metal ion as evidenced by as shift of nu(1)(A) to higher frequency ad splitting of doubly degenerate (E) modes. The observed values of magnetic moments and the band positions in the electronic spectra of these compounds are consistent with the octahedral geometry such that the SO3Cl- group is coordinated in a bidentate manner to the metal ions.

  DOI：

  10.1080/00945719608004771