3-[4-[4-[(2-hydroxy-3-methoxyphenyl)methylideneamino]phenyl]phenyl]imino-N-phenylbutanamide | 1278424-66-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3-[4-[4-[(2-hydroxy-3-methoxyphenyl)methylideneamino]phenyl]phenyl]imino-N-phenylbutanamide
• CAS: 1278424-66-0
• 化学式: C₃₀H₂₇N₃O₃
• 分子量: 477.563
• InChiKey: KDYKAYZFHFRJGJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.3
• 重原子数：
  36
• 可旋转键数：
  8
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.1
• 拓扑面积：
  83.3
• 氢给体数：
  2
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  邻香草醛 、 N-乙酰乙酰苯胺 、 联苯胺 以 甲醇 为溶剂， 生成 3-[4-[4-[(2-hydroxy-3-methoxyphenyl)methylideneamino]phenyl]phenyl]imino-N-phenylbutanamide
  参考文献：
  名称：

  Binuclear Ruthenium(II) Carbonyl Schiff Base Complexes Containing N₂O₂ Donors and their Catalytic and Biological Activities

  摘要：

  An interesting series of binuclear ruthenium(II) Schiff base complexes of the type [RuCl(CO)(EPh3)2(B)]2L (where E[image omitted]P/As; B[image omitted]PPh3/AsPh3/Py; L[image omitted]binucleating monobasic bidendate Schiff base ligand) have been synthesized by reacting [RuCl(CO)(EPh3)2(B)]2 with Schiff bases derived from acetoacetanilide and salicylaldehyde/o-hydroxyacetophenone/o-vanillin/2-hydroxy-1-naphthaldehyde with benzene. The complexes were characterized by analytical, spectroscopic, and electrochemical measurements. The new diamagnetic ruthenium(II) complexes have N2O2 metal binding sites, which are linked to each other with a biphenyl bridge and act as potential catalyst for the oxidation of wide range of primary and secondary alcohols to corresponding aldehydes and ketones in the presence of molecular oxygen and also in CC coupling reactions. Further, the antibacterial properties of the free ligands and their metal complexes were evaluated against certain bacteria such as Escherichia Coli and Staphylococcus aureus.

  DOI：

  10.1080/15533174.2010.522883