4,10-bis(5-octyl-2-thienyl)anthanthrone | 1421229-75-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 芘
• 英文名称: 4,10-bis(5-octyl-2-thienyl)anthanthrone
• 英文别名: 9,18-Bis(5-octylthiophen-2-yl)hexacyclo[11.7.1.14,20.02,11.03,8.017,21]docosa-1(21),2,4,6,8,10,13,15,17,19-decaene-12,22-dione
• CAS: 1421229-75-5
• 化学式: C₄₆H₄₆O₂S₂
• 分子量: 695.002
• InChiKey: SPMLGZBPQMOVGL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  15.6
• 重原子数：
  50
• 可旋转键数：
  16
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.35
• 拓扑面积：
  90.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  4,10-bis(5-octyl-2-thienyl)anthanthrone 、 4-辛基苯胺 在 三乙烯二胺 、 四氯化钛 作用下， 以 邻二氯苯 为溶剂， 反应 3.17h， 以57%的产率得到4,10-bis(5-octylthiophen-2-yl)-N⁶,N¹²-bis(4-octylphenyl)-dihydroanthanthrene-6,12-diimine
  参考文献：
  名称：

  Synthesis and Optoelectronic Properties of 6,12-Bis(amino)anthanthrene Derivatives

  摘要：

  A series of 6,12-bis(amino) anthanthrene-based conjugated molecules were prepared and characterized using UV-vis and fluorescence spectroscopy and cyclic voltammetry. The absorption spectra and redox potentials of these molecules can be modulated by changing the conjugated moieties linked at the 4 and 10 positions. Moreover, the optoelectronic properties of these derivatives strongly depend on the moieties attached to the nitrogen atoms at the 6 and 12 positions.

  DOI：

  10.1021/jo402313c
• 作为产物：
  描述：

  2-正辛基噻吩 、 还原亮橙IRK 在 正丁基锂 、 三丁基氯化锡 、 bis-triphenylphosphine-palladium(II) chloride 作用下， 以 四氢呋喃 、 正己烷 为溶剂， 反应 3.0h， 以77%的产率得到4,10-bis(5-octyl-2-thienyl)anthanthrone
  参考文献：
  名称：

  4,10-二溴蒽蒽酮是p型，n型和双极性π共轭材料的新构件

  摘要：

  新的p型，n型和双极性分子是由市售的4,10-二溴蒽蒽酮染料合成的。用不同的富电子和贫电子单元取代4,10和6,12位可以调节分子的光电特性。还制备了双（二氰基亚乙烯基）官能化的化合物，相对于具有结晶二维层状堆积排列的Ag +而言，其还原电位低至-50 mV 。这些特性是空气稳定的n型有机场效应晶体管应用的重要先决条件。

  DOI：

  10.1002/chem.201202878

文献信息

• ORGANIC FILM TRANSISTOR, ORGANIC SEMICONDUCTOR FILM, AND ORGANIC SEMICONDUCTOR MATERIAL AND USE APPLICATIONS THEREOF
  申请人：FUJIFILM Corporation

  公开号：US20160126460A1

  公开（公告）日：2016-05-05

  An organic film transistor containing a compound, which is composed of n repeating units represented by Formula (1-1), (1-2), (101-1), or (101-2), in a semiconductor active layer is an organic film transistor using a compound having high carrier mobility and high solubility in an organic solvent. (Cy represents a benzene ring, a naphthalene ring, or an anthracene ring; each of R 11 to R 14 and R 15 to R 18 independently represents a hydrogen atom or a substituent; each of Ar 1 to Ar 4 independently represents a heteroarylene group or an arylene group; each of V 1 and V 2 represents a divalent linking group; m represents an integer of 0 to 6; when m is equal to or greater than 2, two or more groups represented by V 1 may be the same as or different from each other; n is equal to or greater than 2; p represents an integer of 0 to 6; and when p is equal to or greater than 2, two or more groups represented by V 2 may be the same as or different from each other.)
• US9508934B2
  申请人：——

  公开号：US9508934B2

  公开（公告）日：2016-11-29