| 1428675-67-5

• 分子结构分类: 有机化合物 - 有机杂环化合物
• CAS: 1428675-67-5
• 化学式: C₂₀H₁₈Br₂N₄
• 分子量: 474.198
• InChiKey: XZFXXGPNNDZYIC-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  1,1,5,5-tetramethyl-3-bromo-1,5-diazapentadienium perchlorate 、 3,4-二氨基甲苯 在 溶剂黄146 作用下， 以 乙醇 为溶剂， 反应 12.5h， 生成 、
  参考文献：
  名称：

  Synthesis of New Dibenzo-tetraaza and Dibenzo-dioxadiaza[14]annulene Derivatives Using 3-Bromo-substituted Vinamidinium Salt

  摘要：

  Novel bromo-substituted derivatives of dibenzo-tetraaza and dibenzo-dioxadiaza[14]annulenes BG were synthesized by a twofold condensation reaction of a symmetrical bromo-substituted vinamidinum salt A with ortho-diamino- and ortho-amino-hydroxyarenes such as 1,2-diaminobenzene, 1,2-diamino-4,5-dimethylbenzene, 2,3-diaminonaphthalene, 1,2-diamino-4-methylbenzene, 2-amino-1-hydroxybnzene, and 2-amino-1-hydroxy-5-methyl-benzene in acetonitrile/acetic acid as reaction medium. The ultraviolet/visible spectral behavior of these [14]annulenes was examined in dimethyl sulfoxide (DMSO). Elemental analysis, infrared, H-1 NMR, C-13 NMR, and mass spectra confirm the molecular structure of the newly synthesized compounds.

  DOI：

  10.1080/00397911.2012.681826