1,2,3-tris-ethoxycarbonyloxy-propane | 70873-67-5

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 甘油脂
• 英文名称: 1,2,3-tris-ethoxycarbonyloxy-propane
• 英文别名: Glycerin-O.O.O-tricarbonsaeure-triaethylester；Glycerintrikohlensaeure-triaethylester；1,2,3-Tris-aethoxycarbonyloxy-propan；O.O.O-Tricarbaethoxy-glycerin；1,3-Bis(ethoxycarbonyloxy)propan-2-yl ethyl carbonate
• CAS: 70873-67-5
• 化学式: C₁₂H₂₀O₉
• 分子量: 308.285
• InChiKey: IBNNPNVPHMYCFX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  21
• 可旋转键数：
  14
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  107
• 氢给体数：
  0
• 氢受体数：
  9

反应信息

• 作为反应物：
  描述：

  1,2,3-tris-ethoxycarbonyloxy-propane 在 barium dihydroxide 、 乙醇 作用下， 生成 4-hydroxy-2,6-dioxa-heptanedioic acid diethyl ester
  参考文献：
  名称：

  Allpress; Maw, Journal of the Chemical Society, 1924, vol. 125, p. 2261

  摘要：

  DOI：
• 作为产物：
  描述：

  氯甲酸乙酯 、 甘油 在 吡啶 、 氯仿 作用下， 生成 1,2,3-tris-ethoxycarbonyloxy-propane
  参考文献：
  名称：

  Allpress; Maw, Journal of the Chemical Society, 1924, vol. 125, p. 2261

  摘要：

  DOI：

文献信息

• Verfahren zur Hydrierung von Zitronensäure
  申请人：BASF Aktiengesellschaft

  公开号：EP0591795A1

  公开（公告）日：1994-04-13

  Verfahren zur Herstellung von Propan-1,2,3-tricarbonsäure, Tetrahydrofurylessigsäure und deren C₁- bis C₂₀-Alkyl- oder C₇- bis C₁₂-Aralkylester, Propan-1,2,3-trimethanol, 3-Methyltetrahydrofuran, 3-(2'-Hydroxyethyl)tetrahydrofuran, 4-Hydroxymethyltetrahydropyran, 2-Methyl-γ-butyrolacton und/oder 3-Methyl-γ-butyrolacton, indem man Zitronensäure oder deren C₁- bis C₂₀-Alkyl- oder C₇- bis C₁₂-Aralkylester in nicht-wäßrigen Lösungsmitteln bei Temperaturen von 50 bis 400°C und Drücken von 1 bis 400 bar an Hydrierkatalysatoren umsetzt.

  丙烷-1,2,3-三羧酸、四氢呋喃乙酸及其 C₁-至 C₂₀-烷基或 C₇-至 C₁₂-烷基酯、丙烷-1,2,3-三甲醇、3-甲基四氢呋喃、3-(2'-羟乙基)四氢呋喃、4-羟甲基四氢吡喃的制备工艺、柠檬酸或其 C₁-至 C₂₀-烷基或 C₇- 至 C₁₂- 芳烷基酯在非水溶剂中与氢化催化剂在 50 至 400°C 温度和 1 至 400 巴压力下发生反应，制得 2-甲基-γ-丁内酯和/或 3-甲基-γ-丁内酯。
• ADJUVANTS
  申请人：SYNGENTA LIMITED

  公开号：US20150250163A1

  公开（公告）日：2015-09-10

  This invention relates to a composition comprising an agrochemical and a compound of formula (I) wherein each A is independently selected from C 1-10 alkanediyl; n is an integer selected from 0 to 45 inclusive; and m is an integer selected from 1, 2, 3 and 4; R is a branched or linear C 1 -C 24 hydrocarbon either fully saturated or comprising up to three double bonds or is phenyl or is benzyl or is a C 3 -C 8 fully saturated cyclic group; and R is substituted 1, 2, 3 or 4 times as defined by the value of m; and when m is 1 and n is not zero, R may also be hydrogen; and Q is a branched or linear C 1 -C 24 hydrocarbon either fully saturated or comprising up to three double bonds or is phenyl or is benzyl or is a C 3 -C 8 fully saturated cyclic group; provided that when m is 1 and n is zero, Q and R are not both selected from a branched or linear C 1 -C 24 hydrocarbon either fully saturated or comprising up to three double bonds to methods of making and using the compositions; and to the use of the compounds as adjuvants for agrochemical use. In particular the present invention relates to compositions selected from an emulsion concentrate (EC), an emulsion in water (EW), a suspension of particles in water (SC), a soluble liquid (SL), a microcapsule formulation (CS), a suspension of particles with an emulsion (SE), a dispersion concentrate (DC), an oil suspension (OD), a water dispersible granule (WG), a soluble granule (SG) and a wettable powder (WP).
• US9456599B2
  申请人：——

  公开号：US9456599B2

  公开（公告）日：2016-10-04