[Zn(2-(1H-benzo[d]imidazol-2-yl)-6-methoxyohenol)(pyridine)Yb(NO3)3] | 1388121-51-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: [Zn(2-(1H-benzo[d]imidazol-2-yl)-6-methoxyohenol)(pyridine)Yb(NO3)3]
• CAS: 1388121-51-4
• 化学式: C₃₃H₂₇N₈O₁₃YbZn
• 分子量: 982.053
• InChiKey: HURWHBFGIHIJTI-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  ytterbium(III) nitrate pentahydrate 、 [Zn(2-(1H-benzo[d]imidazol-2-yl)-6-methoxyohenol)(pyridine)] 以 not given 为溶剂， 生成 [Zn(2-(1H-benzo[d]imidazol-2-yl)-6-methoxyohenol)(pyridine)Yb(NO3)3]
  参考文献：
  名称：

  Hetero-binuclear near-infrared (NIR) luminescent ZnLn (Ln = Nd, Yb or Er) complexes self-assembled from the benzimidazole-based ligand

  摘要：

  With the [Zn(HL)(2)(Py)] compound from the benzimidazole-based ligand H2L (H2L: 2-(1H-benzo[d]imidazol-2-yl)-6-methoxyohenol) as the precursor, the series of four hetero-binuclear ZnLn arrayed complexes IZnLn(HL)(2)(PONO3)(3)](Ln = Nd, 1; Ln = Yb, 2; Ln = Er, 3; Ln = Gd, 4) have been obtained by the further reaction with Ln(NO3)(3)center dot 6H(2)O, respectively. The result of their photophysical properties shows that the strong and characteristic NIR luminescence of Nd3+ or Yb3+ ion with emissive lifetimes in microsecond range, has been sensitized from the excited state ((LC)-L-1 and (LC)-L-3) of the benzimidazole-based ligand. (C) 2012 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2012.05.041