| 1332646-25-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• CAS: 1332646-25-9
• 化学式: C₁₀₀H₁₁₈O₂₀
• 分子量: 1640.02
• InChiKey: MLXCWDQSQUXTFV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  19.73
• 重原子数：
  120.0
• 可旋转键数：
  33.0
• 环数：
  30.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  184.6
• 氢给体数：
  0.0
• 氢受体数：
  20.0

反应信息

• 作为反应物：
  描述：

  n-octyltrimethyl ammonium hexafluorophosphate 、 以 氘代氯仿 为溶剂， 生成
  参考文献：
  名称：

  Synthesis of a pillar[5]arene dimer by co-oligomerization and its complexation with n-octyltrimethyl ammonium hexafluorophosphate

  摘要：

  A pillar[5]arene dimer was successfully prepared by co-oligomerization of 1,4-dimethoxybenzene and 1.6-bis(4-butoxyphenoxy)hexane. It was demonstrated that it forms 1:2 complexes with n-octyltrimethyl ammonium hexafluorophosphate both in chloroform and the gaseous state. A Scatchard plot indicated that the complexation between them is statistical with an average association constant of 6.0 (+/- 0.4) x 10(2) M-1 in chloroform. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2011.06.065
• 作为产物：
  描述：

  聚合甲醛 、 1,6-bis(4-butoxyphenoxy)hexane 、 对苯二甲醚 在 三氟化硼乙醚 作用下， 以 1,2-二氯乙烷 为溶剂， 反应 5.0h， 以8%的产率得到
  参考文献：
  名称：

  Synthesis of a pillar[5]arene dimer by co-oligomerization and its complexation with n-octyltrimethyl ammonium hexafluorophosphate

  摘要：

  A pillar[5]arene dimer was successfully prepared by co-oligomerization of 1,4-dimethoxybenzene and 1.6-bis(4-butoxyphenoxy)hexane. It was demonstrated that it forms 1:2 complexes with n-octyltrimethyl ammonium hexafluorophosphate both in chloroform and the gaseous state. A Scatchard plot indicated that the complexation between them is statistical with an average association constant of 6.0 (+/- 0.4) x 10(2) M-1 in chloroform. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2011.06.065