(DABCO)(3.6.9-trioxaundecane-1,11-bis[2,8,12,18-tetrabutyl-3,7,13,17-tetrametyl-5-(3-oxyphenyl)porphyrinatozinc(II)]) | 1246291-05-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: (DABCO)(3.6.9-trioxaundecane-1,11-bis[2,8,12,18-tetrabutyl-3,7,13,17-tetrametyl-5-(3-oxyphenyl)porphyrinatozinc(II)])
• CAS: 1246291-05-3
• 化学式: C₁₀₆H₁₃₈N₁₀O₅Zn₂
• 分子量: 1763.11
• InChiKey: STWNAKICCYTTPP-HXDUFMLGSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  三乙烯二胺 、 bis[5-(3-oxyphenyl)-2,2,12,18-tetrabutyl-3,7,13,17-tetramethylporphyrinatozinc(II)]-3,6,9-trioxyundecane-1,11 以 toluene 、 methanol 为溶剂， 生成 (DABCO)(3.6.9-trioxaundecane-1,11-bis[2,8,12,18-tetrabutyl-3,7,13,17-tetrametyl-5-(3-oxyphenyl)porphyrinatozinc(II)])
  参考文献：
  名称：

  Complexing ability of dimeric zinc octaalkylporphyrinates with a poly(ethyleneoxy) bridge toward 1,4-diazabicyclo[2.2.2]octane and 1,4-diazine

  摘要：

  The formation of "guest-host" complexes from dimeric zinc octaalkylporphyrinates with a poly(ethyleneoxy) bridge and various bidentate ligands containing two N atoms was studied by spectrophotometric titration and H-1 NMR spectroscopy in toluene-methanol (5: 1). The reactions of dimeric porphyrinates with 1,4-diazabicyclo[2.2.2]octane and 1,4-diazine gave 1: 1 or 1: 2 complexes, depending on the molar ratio of metal porphyrin and the ligand. The stability constants of the complexes obtained and the concentration ranges for their formation were determined.

  DOI：

  10.1134/s1070328410040111