3',4'-Dichlor-2,2-dimethyl-valeriansaeureanilid | 7132-29-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3',4'-Dichlor-2,2-dimethyl-valeriansaeureanilid
• 英文别名: N-(3,4-dichlorophenyl)-α,α-dimethylvaleramide；N-(3,4-dichlorophenyl)-a,a-dimethylvaleramide；N-(3,4-dichlorophenyl)-alpha,alpha-dimethylvaleramide；N-(3,4-dichlorophenyl)-2,2-dimethylpentanamide
• CAS: 7132-29-8
• 化学式: C₁₃H₁₇Cl₂NO
• 分子量: 274.19
• InChiKey: IEPVFABAADVNMN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.8
• 重原子数：
  17
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.46
• 拓扑面积：
  29.1
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  丙草胺 、 敌稗 、 丁酰草胺 、 戊酰苯草胺 、 3,4-二氯-N-特戊酰基苯胺 、 3',4'-Dichlor-2,2-dimethyl-valeriansaeureanilid 、 毒草胺 、 丁草胺 、 甲草胺 生成 异丙甲草胺
  参考文献：
  名称：

  Herbicidal 1-(disubstituted

  摘要：

  本发明涉及式子为##STR1##的1-(二取代氨基甲酰基)-3-(N-芳基磺酰氨基)-1,2,4-三唑类化合物，其中R.sup.1和R.sup.2各自独立选择自烷基、烯基、炔基、环烷基、环烷基烷基、环烯基、环烯基烷基、卤代烷基、烷氧基烷基和卤代烷氧基烷基的群体中的一种；R.sup.3是氢、烷基、烯基、炔基、环烷基、环烷基烷基、环烯基、环烯基烷基、卤代烷基、烷氧基烷基或卤代烷氧基烷基；Ar是可选取代的芳基基团；以及这些化合物的农业上可接受的酸盐和金属络合物、含有这些化合物的组合物以及它们作为除草剂的用途。

  公开号：

  US05258361A1

文献信息

• Herbicidal-1-(disubstituted carbamoyl or
  申请人：Rohm and Haas Company

  公开号：US05211739A1

  公开（公告）日：1993-05-18

  This invention relates to 1-(disubstituted carbamoyl or thiocarbamoyl)-1,2,4-triazol-3-yl sulfonates and thiosulfonates of the formula ##STR1## wherein R.sup.1 and R.sup.2 are each independently selected from the group consisting of optionally substituted alkyl, alkenyl, alkynyl, cycloalkyl, cycloalkenyl and cycloalkynyl, or they may together with the nitrogen to which they are attached form an optionally substituted heterocyclic ring, R.sup.3 is an optionally substituted alkyl, cycloalkyl, alkenyl, cycloalkenyl, aryl, aralkyl or aromatic heterocyclic group, X and Y are each independently oxygen or sulfur, and the agronomically acceptable acid addition salts and metal complexes thereof, compositions containing these compounds and their uses as herbicides.

  本发明涉及1-(二取代氨基甲酰基或硫氨基甲酰基)-1,2,4-三唑-3-基磺酸盐和硫代磺酸盐的化合物，其化学式为##STR1##其中R.sup.1和R.sup.2各自独立地选自选配取代的烷基、烯基、炔基、环烷基、环烯基和环炔基，或者它们可以与它们附着的氮一起形成选配取代的杂环环，R.sup.3是选配取代的烷基、环烷基、烯基、环烯基、芳香族、芳香基烷基或芳香族杂环基，X和Y各自独立地是氧或硫，以及其农学上可接受的酸加成盐和金属配合物、含有这些化合物的组合物和它们作为除草剂的用途。
• 6-arylpyrimidines and herbicidal use
  申请人：Rohm and Haas Company

  公开号：US05298481A1

  公开（公告）日：1994-03-29

  A class of 6-arylpyrimidines which is useful in the control of weeds is of the general formulae: ##STR1## wherein R.sup.2 is selected from hydrogen, halo, substituted or unsubstituted alkyl, haloalkyl, polyhaloalkyl, haloalkenyl, polyhaloalkenyl, haloalkynyl, polyhaloalkynyl, alkenyl, alkynyl, alkoxy, alkylthio, alkoxycarbonylalkyl, cyano, alkoxyalkyl, alkoxycarbonyl, cycloalkyl, aralkyl, alkylamino, dialkylamino, or dialkylaminocarbonyl group; R.sup.3 is an alkyl, alkenyl, alkynyl, or haloalkyl group; R.sup.5 is an alkyl, alkenyl, alkynyl, alkenynyl, or alkoxyalkyl, group; R.sup.6 is an aryl group (e.g. aromatic ring); and X is oxygen or sulfur. R.sup.2 and R.sup.3 may form a fused ring.

  一类6-芳基嘧啶类化合物可用于除草，其一般式为：##STR1## 其中R.sup.2选自氢、卤素、取代或未取代的烷基、卤代烷基、多卤代烷基、卤代烯基、多卤代烯基、卤代炔基、多卤代炔基、烯基、炔基、烷氧基、烷硫基、烷氧羰基烷基、氰基、烷氧基烷基、烷氧羰基、环烷基、芳基烷基、烷基氨基、二烷基氨基或二烷基氨基羰基基团；R.sup.3是烷基、烯基、炔基或卤代烷基基团；R.sup.5是烷基、烯基、炔基、烯炔基或烷氧基烷基基团；R.sup.6是芳基基团（例如芳环）；X是氧或硫。 R.sup.2和R.sup.3可以形成融合的环。
• Halopyridyl triazolinone herbicides and herbicidal use thereof
  申请人：Rohm and Haas Company

  公开号：US05733849A1

  公开（公告）日：1998-03-31

  Disclosed are herbicidal halopyridyl triazolinones, herbicidal compositions comprising the halopyridyl triazolinones, and herbicidal use of the compounds and compositions. Such compounds and compositions are useful as both preemergence and postemergence herbicides in a variety of crops.

  本发明涉及除草的卤代吡啶基三唑啉酮，包含该卤代吡啶基三唑啉酮的除草组合物，以及该化合物和组合物的除草用途。这种化合物和组合物在各种农作物中作为早期和后期除草剂都很有用。
• Herbicidally active enols
  申请人：ROHM AND HAAS COMPANY

  公开号：EP0213892A2

  公开（公告）日：1987-03-11

  Eriols having the formula wherein A, B, O, V and W are as defined herein, their geometric isomers and tautomers, halogen addition products thereof, and agriculturally acceptable salts of the foregoing and compositions containing these compounds, exhibit herbicidal activity.

  具有以下式子的烯醇 其中 A、B、O、V 和 W 如本文所定义，它们的几何异构体和同素异形体、它们的卤素加成产物，以及上述化合物的农业上可接受的盐和含有这些化合物的组合物具有除草活性。
• Phosphosulfonate herbicides
  申请人：ROHM AND HAAS COMPANY

  公开号：EP0511826A2

  公开（公告）日：1992-11-04

  This invention concerns phosphosulfonates having the general formula wherein (1) Y is phenyl ; naphthyl ; benzyl ; (C5-C8)cycloalkyl ; a 5-membered heteroaromatic ring having from one to four heteroatoms each being independently N, O or S, provided that no more than one is O or S ; a 6-membered heteroaromatic ring having 1, 2 or 3 nitrogen atoms ; or a fused 5,6- or 6,6-membered heteroaromatic ring having from one to four heteroatoms each being independently N, O or S, provided that no more than one is O or S ; wherein Y optionally has up to three substituents, each being independently halogen, cyano, nitro, (C1-C6)alkoxy, halo(C1-C4)alkoxy, (C1-C6)alkyl, halo(C1-C4)alkyl, phenyl, (C1-C4)alkylcarbonyloxy, di(C1-C4)alkylcarbamoyl or (C1-C4)alkoxycarbonyl, provided that (a) no more than one of said substituents is present when Y is a thiadiazolyl ring or a tetrazolyl ring, and (b) no more than two of said substituents is present when Y is a triazolyl ring, a thiazolyl ring, or an isothiazolyl ring, except that when Y is phenyl, naphthyl or benzyl, it may have up to five substituents each being independently halogen, acetoxy, methyl, methoxy or halomethoxy, but no more than two of which are acetoxy, methyl, methoxy, or halomethoxy; (2) X is oxygen or sulfur ; and (3) R1 and R2 are each independently chloro, or (C1-C6)alkyl, (C1-C6)alkoxy, halo(C2-C4)alkoxy, (C1-C4)alkylthio, (C3-C4)alkenyloxy, (C3-C4)alkynyloxy, (C1-C4)alkoxy(C1-C4)alkoxy, (C4-C8)cycloalkyloxy, (C3-C6)cycloalkyl(C1-C3)alkoxy, cyano(C1-C4)alkoxy, (C2-C4)alkylideneiminooxy or amino each optionally substituted with one or two of (C1-C4)alkyl, (C2-C4)alkenyl or phenyl ; provided that there is not more than one phenyl group on the amino group ; also provided that R1 may additionally be phenyl or phenoxy; and also provided that R1 and R2 may both be alkoxy so as to form together with the phosphorus atom a 6-membered oxygen-containing ring ; except that when R1 and R2 are both alkoxy, Y is not phenyl, 4-methylphenyl, 4-chlorophenyl, 4-bromophenyl or 3-nitrophenyl ; compositions containing these compounds and their use as herbicides.

  本发明涉及通式如下的磷磺酸盐 其中 (1) Y 是苯基；萘基；苄基；(C5-C8)环烷基；具有 1 至 4 个杂原子的 5 元杂芳环，每个杂原子独立地为 N、O 或 S，但 O 或 S 不超过一个；具有 1、2 或 3 个氮原子的 6 元杂芳环；或融合的 5、6 或 6、6 元杂芳环，其 1 至 4 个杂原子各自独立地为 N、O 或 S，但 O 或 S 原子不得多于 1 个； 其中 Y 可任选具有最多三个取代基，每个取代基独立为卤素、氰基、硝基、(C1-C6)烷氧基、卤代(C1-C4)烷氧基、(C1-C6)烷基、卤代(C1-C4)烷基、苯基、(C1-C4)烷基羰氧基、二(C1-C4)烷基氨基甲酰基或(C1-C4)烷氧基羰基，条件是 (a) 当 Y 为噻二唑环或四唑环时，上述取代基中存在的不超过一个，且 (b) 当 Y 为三唑环、噻唑环或异噻唑环时，所述取代基不超过两个，但当 Y 为苯基、萘基或苄基时，最多可有五个取代基，每个取代基独立地为卤素、乙酰氧基、甲基、甲氧基或卤代甲氧基，但其中乙酰氧基、甲基、甲氧基或卤代甲氧基不超过两个； (2) X 是氧或硫；以及 (3) R1 和 R2 各自独立地是氯、或 (C1-C6)烷基、(C1-C6)烷氧基、卤代(C2-C4)烷氧基、(C1-C4)烷硫基、(C3-C4)烯氧基、(C3-C4)炔氧基、(C1-C4)烷氧基（C1-C4）烷氧基、(C4-C8)环烷氧基、(C3-C6)环烷基(C1-C3)烷氧基、氰基(C1-C4)烷氧基、(C2-C4)亚烷基亚氨基氧基或氨基，各自任选被一个或两个(C1-C4)烷基、(C2-C4)烯基或苯基取代；前提是氨基上的苯基不超过一个；此外，R1 还可以是苯基或苯氧基；R1 和 R2 还可以都是烷氧基，以便与磷原子一起形成一个 6 元含氧环；但当 R1 和 R2 都是烷氧基时，Y 不是苯基、4-甲基苯基、4-氯苯基、4-溴苯基或 3-硝基苯基；含有这些化合物的组合物及其作为除草剂的用途。