| 1417307-06-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• CAS: 1417307-06-2
• 化学式: C₆₀H₈₆O₈
• 分子量: 935.338
• InChiKey: LYNWXLOEEYJQEW-UHFFFAOYSA-N

物化性质

• 沸点：
  935.5±60.0 °C(Predicted)
• 密度：
  1.045±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  17.38
• 重原子数：
  68.0
• 可旋转键数：
  39.0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.58
• 拓扑面积：
  81.68
• 氢给体数：
  0.0
• 氢受体数：
  8.0

反应信息

• 作为反应物：
  描述：

  、 5,11,17,23-tetra-tert-butyl-25,27-dihydroxy-26,28-bis[(hydrazidocarbonylmethyl)oxy]calix[4]-arene 以 甲醇 、 氯仿 为溶剂， 反应 8.0h， 以86%的产率得到
  参考文献：
  名称：

  Ion complexation-induced mesomorphic conversion between two columnar phases of novel symmetrical triads of triphenylene-calix[4]arene-triphenylenes

  摘要：

  Two novel symmetrical triads of triphenylene-calix[4]arene-triphenylenes 6a and 6b bridged by hydrazone spacers were synthesized in high yields. They possessed interesting ion complexation-induced mesomorphic conversion between two columnar phases. The neat compounds 6a and 6b showed mesophase with calixarene's bowlic column as cores. The Ag+-complexes of 6a and 6b exhibited mesophase with triphenylene column as cores. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2012.11.029
• 作为产物：
  描述：

  1,10-二溴癸烷 、 2-hydroxy-3,6,7,10,11-pentapentyloxytriphenylene 在 potassium carbonate 作用下， 以 乙腈 为溶剂， 生成
  参考文献：
  名称：

  Ion complexation-induced mesomorphic conversion between two columnar phases of novel symmetrical triads of triphenylene-calix[4]arene-triphenylenes

  摘要：

  Two novel symmetrical triads of triphenylene-calix[4]arene-triphenylenes 6a and 6b bridged by hydrazone spacers were synthesized in high yields. They possessed interesting ion complexation-induced mesomorphic conversion between two columnar phases. The neat compounds 6a and 6b showed mesophase with calixarene's bowlic column as cores. The Ag+-complexes of 6a and 6b exhibited mesophase with triphenylene column as cores. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2012.11.029