N,N'-bis(2-pyridylethyl)oxamide | 41012-36-6

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: N,N'-bis(2-pyridylethyl)oxamide
• 英文别名: bis(2-(2-pyridyl)ethyl)oxamide；N,N'-bis-(2-pyridin-2-yl-ethyl)-oxalamide；N,N'-bis(2-pyridyl-ethyl)oxamide；N,N'-bis(2-pyridin-2-ylethyl)oxamide
• CAS: 41012-36-6
• 化学式: C₁₆H₁₈N₄O₂
• 分子量: 298.345
• InChiKey: GOCPVVBOZSSHOO-UHFFFAOYSA-N

物化性质

• 密度：
  1.206±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.1
• 重原子数：
  22
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  84
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  copper(II) acetate monohydrate 、 N,N'-bis(2-pyridylethyl)oxamide 以 乙醇 为溶剂， 以80%的产率得到[μ-N,N'-bis(2-(2-pyridyl)ethyl)oxamidate]bis[acetatocopper(II)]
  参考文献：
  名称：

  [μ-N,N'-Bis(2-pyridylethyl)oxamide]bis[acetatocopper(II)]

  摘要：

  The structure of the title compound, [Cu-2(CH3COO)(2-)(C16H16N4O2)], was determined by single-crystal X-ray diffraction and revealed binuclear complex molecules which lie about. inversion centers. The Cu-II atom has square-pyramidal coordination, with an additional nonbonded Cu ... O contact of 2.818 (4) Angstrom , which helps the maintenance of the crystal packing.

  DOI：

  10.1107/s0108270199009476

文献信息

• Metal complexes with disubstituted oxamidic ligands
  作者：U. Casellato、P. Guerriero、S. Tamburini、P.A. Vigato

  DOI：10.1016/s0020-1693(96)05520-x

  日期：1997.7

  Three oxamidic ligands have been prepared by reaction of oxalyldichloride with the appropriate amine H2NC6H4P(C6H5)(2) (H(2)A), H2NC2H4(NC5H4) (H2B) and H2NC2H4SC6H5 (H2C). They have been characterized by elemental analyses, IR, NMR, mass spectrometry and for H2B by X-ray diffractometry. The crystals, grown from a tetrahydrofuran/diethylether solution, are monoclinic, space group P2(1)/c, cell dimensions a=9.503(4), b=6.278(4), c=13.083(5) Angstrom and beta=100.24(4)degrees with Z=2. The asymmetric unit is half of the ligand molecule which shows an inversion centre between the C-C bond of the oxamidic group. The molecule is elongated in a three steps configuration. The reaction of H(2)A with trans-Pd(C6H5CN)(2)(Cl)(2) forms the white mononuclear cis-Pd(A) and the yellow homodinuclear trans-Pd-2(A)(Cl)(2) complexes as confirmed by scanning electron microscopy (SEM) and EDX analyses and by an X-ray structure of Pd-2(A)(C)(2). The yellow crystals, grown from alcoholic solution, are monoclinic, space group P2(1)/c, cell dimensions a=10.335(5), b=10.246(5), c=16.480(6) Angstrom and beta=100.81(5)degrees with Z=2; as for H2B crystals, the asymmetric unit is half of the whole molecule. A distorted square planar coordination around each metal ion is reached by the coordination of a phosphorus, an oxygen and a nitrogen atom of the ligand and a chlorine atom. H2B forms the homodinuclear nickel(II) and copper(II) complexes M(B)(X)(2) (X=Cl-, CH3COO-, ClO4-). Crystals of the dinuclear copper(II) complex Cu-2(B) (Cl)(2)(dmso)(2) grown from dimethylsulphoxide, are triclinic, space group P (1) over bar, cell dimensions a=8.352(5), b=8.361(5), c=9.959(4) Angstrom, alpha=83.39(4) beta=85.49(3), gamma=75.38(5)degrees with Z=1. Again the dinuclear entity shows a inversion centre between the two C-C bonds of the oxamide ligand. Each copper(II) ion has a distorted square pyramidal environment formed by two nitrogen atom and an oxygen atom of half oxamidic ligand, a chlorine atom and the oxygen atom of a dimethylsulphoxide molecule; the copper-copper distance is 5.28 Angstrom. An antiferromagnetic interaction was observed for the dinuclear copper(II) complexes. H2C does not form complexes when reacted with transition metal ions.