| 1352079-73-2

• 分子结构分类: 有机化合物 - 有机杂环化合物
• CAS: 1352079-73-2
• 化学式: C₅₄H₃₆F₁₈N₇U
• 分子量: 1362.93
• InChiKey: WGVXDQUGZITINW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  吡啶 、 在 lithium trimethylstannyl 作用下， 以 四氢呋喃 、 甲苯 为溶剂， 反应 1.0h， 以43%的产率得到
  参考文献：
  名称：

  Extending Stannyl Anion Chemistry to the Actinides: Synthesis and Characterization of a Uranium–Tin Bond

  摘要：

  We have synthesized a rare example of a uranium(IV) stannyl (kappa(4)-N(CH2CH2NSi(Pr-i)(3))(3)U(SnMe3), 1) via transmetalation with LiSnMe3. This complex has been characterized crystallographically and shown to have a U-Sn bond length of 3.3130(3) A, substantially longer than the only other crystallographically observed U-Sn bond (3.166 A). Computational studies suggest that the U-Sn bond in 1 is highly polarized, with significant charge transfer to the stannylate ligand. We briefly discuss plausible mechanistic scenarios for the formation of 1, which may be relevant to other transmetalation processes involving heavy main group atoms. Furthermore, we demonstrate the reducing ability of [SnMe3](-) in the absence of strongly donating ligands on U(IV).

  DOI：

  10.1021/acs.inorgchem.6b00543

文献信息

• Uranium Pyrrolylamine Complexes Featuring a Trigonal Binding Pocket and Interligand Noncovalent Interactions
  作者：Andrew J. Lewis、Ursula J. Williams、James M. Kikkawa、Patrick J. Carroll、Eric J. Schelter

  DOI：10.1021/ic202411f

  日期：2012.1.2

  The syntheses of tri- and tetravalent uranium complexes of the Ar(3)(F)TPA(3-) ligand [Ar(F) = 3,5-bis(trifluoromethyl)phenyl; TPA = tris(pyrrolyl-alpha-methylamine)] are described. Interligand noncovalent interactions between arene groups within the complexes are detected both in the solid state and in solution.