[Ru(η(4)-cyclocta-1,5-diene)(η(5)-P3C2Bu(t)2CH(SiMe3)2)] | 186037-93-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 杂芳族化合物
• 英文名称: [Ru(η(4)-cyclocta-1,5-diene)(η(5)-P3C2Bu(t)2CH(SiMe3)2)]
• 英文别名: [Ru(η4-C8H12)-η-P3C2-t-Bu2-CH(SiMe3)2]；(1Z,5Z)-cycloocta-1,5-diene;[(3,5-ditert-butyl-1,2,4-triphosphol-1-yl)-trimethylsilylmethyl]-trimethylsilane;ruthenium
• CAS: 186037-93-4
• 化学式: C₂₅H₄₉P₃RuSi₂
• 分子量: 599.826
• InChiKey: RSXRJAGGERKGFE-GHDUESPLSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.39
• 重原子数：
  31
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.76
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  [Ru(η(4)-cyclocta-1,5-diene)(η(5)-P3C2Bu(t)2CH(SiMe3)2)] 以 四氢呋喃 为溶剂， 以33%的产率得到
  参考文献：
  名称：

  Novel intramolecular hydrogen-atom transfer in an η⁴-ligated cycloocta-1,5-diene η-1,2,4-triphosphole ruthenium(0) complex. Synthesis, crystal and molecular structures of [Ru(η⁴-C₈H₁₂){η-P₃C₂Bu^t₂[CH(SiMe₃)₂]}] and [Ru(η⁵-C₈H₁₁){η-P₃C₂Bu^t₂H[CH(SiMe₃)₂]}]

  摘要：

  The first known ruthenium(0) complex of a 1,2,4-triphosphole is reported which undergoes a novel hydrogen migration reaction from the eta 4-cycloocta-1,5-diene coligand on heating.

  DOI：

  10.1039/cc9960002751
• 作为产物：
  描述：

  (η6-naphthalene)(η4-1,5-cyclooctadiene)ruthenium(0) 、 1,2,4-triphosphole 以 乙腈 为溶剂， 以62%的产率得到[Ru(η(4)-cyclocta-1,5-diene)(η(5)-P3C2Bu(t)2CH(SiMe3)2)]
  参考文献：
  名称：

  Novel intramolecular hydrogen-atom transfer in an η⁴-ligated cycloocta-1,5-diene η-1,2,4-triphosphole ruthenium(0) complex. Synthesis, crystal and molecular structures of [Ru(η⁴-C₈H₁₂){η-P₃C₂Bu^t₂[CH(SiMe₃)₂]}] and [Ru(η⁵-C₈H₁₁){η-P₃C₂Bu^t₂H[CH(SiMe₃)₂]}]

  摘要：

  The first known ruthenium(0) complex of a 1,2,4-triphosphole is reported which undergoes a novel hydrogen migration reaction from the eta 4-cycloocta-1,5-diene coligand on heating.

  DOI：

  10.1039/cc9960002751

文献信息

• Synthesis of the dicarbonyl ruthenium(0) triphosphole complex [Ru(CO)2{η5-P3C2But2CH(SiMe3)2}] and its conversion into a tricarbonyl complex containing the novel 4-electron donor triphosphorus-ring system {CButPP(H)CH(SiMe3)2CButP(O)H}
  作者：Guy K.B. Clentsmith、Peter B. Hitchcock、John F. Nixon、Nürgun Sakaraya

  DOI：10.1016/s0022-328x(99)00092-3

  日期：1999.7

  1.5-Cyclo-octadiene is readily displaced from [Ru(eta(4)-COD)eta(5)-(P3C2Bu2CH)-C-t(SiMe3)(2)}] to give the dicarbonyl complex [Ru(CO)(2)n(5)-(P3C2Bu2CH)-C-t(SiMe3)(2)}], which on treatment with water in the presence of CO is converted into a tricarbonyl complex containing the novel 4-electron donor triphosphorus-ring system (CBuPP)-P-t(H)CH(SiMe3)(2)(CBuP)-P-t(O)H} which has been structurally characterised. (C) 1999 Elsevier Science S.A. All rights reserved.
• Novel Hydrogen Transfer Reactions to the Ligated 1,2,4-Triphosphole in [Ru(η⁴-C₈H₁₂){η-P₃C₂Bu^t ₂CH(SiMe₃)₂}]
  作者：Peter B. Hitchcock、John F. Nixon、Nurgun Sakarya

  DOI：10.1080/10426509708545685

  日期：1997.1.1