摘要:
Chromium(III) complexes of the type Cr(A)(A')2, Cr(A)2(A') and Cr(A)3 have been prepared (where A is either piperidyldithiocarbamate or morpholyldithiocarbamate and A' is glycine or oxine or acetylacetone moiety). The mixed ligand complexes have been characterized by elemental analyses, magnetic susceptibility measurements and thermal studies. The complexes show magnetic moment in the range of 3.5 - 4.3 B.M. which corresponds to three unpaired electrons. TG studies have also been carried out, in order to study the mode of decomposition of the complexes and to evaluate various kinetic parameters.