N,N'-bis(4-chlorophenyl)-1,7-(disulfuric acid)perylene-3,4,9,10-tetra carboxydiimide | 1200827-15-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: N,N'-bis(4-chlorophenyl)-1,7-(disulfuric acid)perylene-3,4,9,10-tetra carboxydiimide
• 英文别名: 7,18-Bis(4-chlorophenyl)-6,8,17,19-tetraoxo-7,18-diazaheptacyclo[14.6.2.22,5.03,12.04,9.013,23.020,24]hexacosa-1(22),2,4,9,11,13(23),14,16(24),20,25-decaene-11,22-disulfonic acid；7,18-bis(4-chlorophenyl)-6,8,17,19-tetraoxo-7,18-diazaheptacyclo[14.6.2.22,5.03,12.04,9.013,23.020,24]hexacosa-1(22),2,4,9,11,13(23),14,16(24),20,25-decaene-11,22-disulfonic acid
• CAS: 1200827-15-1
• 化学式: C₃₆H₁₆Cl₂N₂O₁₀S₂
• 分子量: 771.568
• InChiKey: QXTCVZIFKFOWHL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.6
• 重原子数：
  52
• 可旋转键数：
  4
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  200
• 氢给体数：
  2
• 氢受体数：
  10

反应信息

• 作为产物：
  描述：

  还原红32 在 发烟硫酸 作用下， 以68.6%的产率得到N,N'-bis(4-chlorophenyl)-1,7-(disulfuric acid)perylene-3,4,9,10-tetra carboxydiimide
  参考文献：
  名称：

  数码纺织印花the酸染料油墨的合成与表征

  摘要：

  合成了五种per酸染料，以制造用于高速喷墨印刷工艺（包括数字纺织品印刷）的水性油墨。与市售的偶氮染料相比，所有合成的per染料均表现出优异的稳定性和光学性能。通过引入庞大和亲水的取代基可有效提高其水溶性，以确保在配制为水性油墨时具有出色的长期稳定性。带有这些per染料的水性油墨具有出色的印刷清晰度，其颜色不同于现有数字纺织印花油墨的基本颜色组成。当在商用喷墨印刷机中使用时，它们还表现出良好的喷射性能，并有助于进行良好控制的图案印刷。

  DOI：

  10.1016/j.dyepig.2018.12.002

文献信息

• HIGH-SATURATION SCARLET COLOR DYE INK FOR HIGH-SPEED INKJET PROCESS
  申请人：KOREA INSTITUE OF INDUSTRIAL TECHNOLOGY

  公开号：US20200109288A1

  公开（公告）日：2020-04-09

  Highly saturated scarlet dye ink for a high-speed inkjet process and a method of preparing the highly saturated scarlet dye ink are disclosed. In particular, an ink composition according to the present invention includes a dye including a compound represented by Formula 1, and further includes, in addition to the dye, distilled water, a surfactant, and an additive. The ink composition develops a highly saturated scarlet color that is unable to be developed by existing inks for digital textile printing (DTP), and has high water solubility, excellent heat resistance, and light-fastness, and thus may be effectively used as dye and ink for a high-speed inkjet process.

  揭示了一种用于高速喷墨工艺的高饱和猩红色染料墨水以及制备该高饱和猩红色染料墨水的方法。具体地，根据本发明的一种墨水组合物包括一种包括由式1表示的化合物的染料，除了染料外，还包括蒸馏水、表面活性剂和添加剂。该墨水组合物开发出一种高饱和猩红色，这种颜色无法由现有的数字纺织品印刷（DTP）墨水开发出来，具有高水溶性、优异的耐热性和耐光性，因此可以有效地用作高速喷墨工艺的染料和墨水。
• The synthesis of thermally-stable red dyes for LCD color filters and analysis of their aggregation and spectral properties
  作者：Chun Sakong、Young Do Kim、Jae-Hong Choi、Chun Yoon、Jae Pil Kim

  DOI：10.1016/j.dyepig.2010.06.003

  日期：2011.2

  Three thermally-stable red dyes of azo, quinacridone and perylene derivatives were synthesized and dye-based color filters were manufactured for use in liquid crystal displays. The aggregation behavior of the dyes and their spectral properties in film state were investigated using field emission scanning electron microscopy and concentration-dependent spectroscopy. Aggregate size was related to the geometry of the three dye types rather than their size, with average aggregate sizes ranging from 35 nm (azo), 80 nm (quinacridone) to 25 nm (perylene). Aggregation behavior affected the spectral property of the red color filter, resulting in weaker and broader transmittance spectrum with higher aggregation. (C) 2010 Elsevier Ltd. All rights reserved.
• The synthesis and characterisation of the perylene acid dye inks for digital textile printing
  作者：Sol Choi、Kwan Hyun Cho、Jin Woong Namgoong、Jeong Yun Kim、Eui Sang Yoo、Woosung Lee、Jae Woong Jung、Jun Choi

  DOI：10.1016/j.dyepig.2018.12.002

  日期：2019.4

  Five perylene acid dyes were synthesized to manufacture water-based inks for the high-speed ink jet printing process, including digital textile printing. All the synthesized perylene dyes exhibited superior stability and optical properties compared to a commercially used azo dye. Their water solubility was efficiently enhanced by introducing bulky and hydrophilic substituents to ensure excellent long-term

  合成了五种per酸染料，以制造用于高速喷墨印刷工艺（包括数字纺织品印刷）的水性油墨。与市售的偶氮染料相比，所有合成的per染料均表现出优异的稳定性和光学性能。通过引入庞大和亲水的取代基可有效提高其水溶性，以确保在配制为水性油墨时具有出色的长期稳定性。带有这些per染料的水性油墨具有出色的印刷清晰度，其颜色不同于现有数字纺织印花油墨的基本颜色组成。当在商用喷墨印刷机中使用时，它们还表现出良好的喷射性能，并有助于进行良好控制的图案印刷。