3-(tert-Butylazo)-3-cyclopropylbutanoic acid | 1027921-83-0

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 3-(tert-Butylazo)-3-cyclopropylbutanoic acid
• CAS: 1027921-83-0
• 化学式: C₁₁H₂₀N₂O₂
• 分子量: 212.292
• InChiKey: URLUTUJYQNBJTL-OUKQBFOZSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.88
• 重原子数：
  15.0
• 可旋转键数：
  4.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.91
• 拓扑面积：
  62.02
• 氢给体数：
  1.0
• 氢受体数：
  3.0

反应信息

• 作为反应物：
  描述：

  叔丁基过氧化氢 、 3-(tert-Butylazo)-3-cyclopropylbutanoic acid 在 N,N'-羰基二咪唑 作用下， 生成 tert-Butyl 3-(tert-butylazo)-3-cyclopropylperbutanoate
  参考文献：
  名称：

  Photolysis of a .beta.-Azo Perester, a Bifunctional Initiator. The Fragmentation Rate of a .beta.-Peroxy Ester Radical Determined by the Cyclopropylcarbinyl Clock Method

  摘要：

  Two free radical initiators containing an azo group and a perester moiety on adjacent carbons have been prepared. On long wavelength W irradiation, these compounds lose nitrogen to afford beta-perester radicals. The cyclopropylcarbinyl radical clock technique has been used to determine that the lifetime of these radicals at 25 degrees C toward beta-scission and decarboxylation is 480 ns. The potential utility of beta-azo peresters as bifunctional free radical initiators is briefly discussed.

  DOI：

  10.1021/jo00093a031
• 作为产物：
  描述：

  (Z)-3-环丙基-2-丁烯酸 在 sodium hydroxide 、 氧气 作用下， 以 水 为溶剂， 反应 7.0h， 生成 3-(tert-Butylazo)-3-cyclopropylbutanoic acid
  参考文献：
  名称：

  Photolysis of a .beta.-Azo Perester, a Bifunctional Initiator. The Fragmentation Rate of a .beta.-Peroxy Ester Radical Determined by the Cyclopropylcarbinyl Clock Method

  摘要：

  Two free radical initiators containing an azo group and a perester moiety on adjacent carbons have been prepared. On long wavelength W irradiation, these compounds lose nitrogen to afford beta-perester radicals. The cyclopropylcarbinyl radical clock technique has been used to determine that the lifetime of these radicals at 25 degrees C toward beta-scission and decarboxylation is 480 ns. The potential utility of beta-azo peresters as bifunctional free radical initiators is briefly discussed.

  DOI：

  10.1021/jo00093a031