2-[[2-[1-(2-Hydroxyphenyl)ethylideneamino]phenyl]iminomethyl]-4-methoxyphenol | 1246564-94-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 2-[[2-[1-(2-Hydroxyphenyl)ethylideneamino]phenyl]iminomethyl]-4-methoxyphenol
• CAS: 1246564-94-2
• 化学式: C₂₂H₂₀N₂O₃
• 分子量: 360.412
• InChiKey: LMNPQBKRLQPNRM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  27
• 可旋转键数：
  5
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.09
• 拓扑面积：
  74.4
• 氢给体数：
  2
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  bis(acetylacetonate)oxovanadium 、 2-[[2-[1-(2-Hydroxyphenyl)ethylideneamino]phenyl]iminomethyl]-4-methoxyphenol 以 甲醇 为溶剂， 以85%的产率得到
  参考文献：
  名称：

  钒基不对称席夫碱配合物的合成，光谱，电化学和热学研究

  摘要：

  合成了新的四齿不对称N 2 O 2 Schiff碱配体和VO（IV）配合物，并通过IR，UV-Vis和元素分析对其进行了表征。通过循环伏安法研究了钒基配合物的电化学性质。根据MeO

  DOI：

  10.1016/j.ica.2010.08.041
• 作为产物：
  描述：

  2'-羟基苯乙酮 以 甲醇 为溶剂， 生成 2-[[2-[1-(2-Hydroxyphenyl)ethylideneamino]phenyl]iminomethyl]-4-methoxyphenol
  参考文献：
  名称：

  钒基不对称席夫碱配合物的合成，光谱，电化学和热学研究

  摘要：

  合成了新的四齿不对称N 2 O 2 Schiff碱配体和VO（IV）配合物，并通过IR，UV-Vis和元素分析对其进行了表征。通过循环伏安法研究了钒基配合物的电化学性质。根据MeO

  DOI：

  10.1016/j.ica.2010.08.041

文献信息

• Synthesis, spectroscopy, electrochemistry and structural determination of asymmetric cobalt(III) Schiff base complexes
  作者：Ali Hossein Kianfar、Maryam Sedighipoor、Gholamhossein Mohammadnezhad、Helmar Görls、Winfried Plass、Mahmoud Roushani

  DOI：10.1007/s13738-016-0979-7

  日期：2017.2

  5-BrMeSalophen, 5-MeOMeSalophen, 4-MeOMeSalophen, 3-MeOMeSalophen and R=Ph or Bu) complexes were synthesized and also characterized by FTIR, UV–Vis, 1H NMR and 13C NMR spectroscopies. The absorptions between 550 and 750 nm for the complexes are attributed to d–d transitions. Electrochemical properties of the complexes were examined by means of cyclic voltammetry. The anodic peak potentials were more

  [CoL（PR 3）（CH 3 OH）] ClO 4（其中L = MeSalophen，5-NO 2 MeSalophen，5-BrMeSalophen，5-MeOMeSalophen，4-MeOMeSalophen，3-MeOMeSalophen和R = Ph或Bu）络合物合成并通过FTIR，UV-Vis，1 H NMR和13 C NMR光谱进行表征。络合物在550至750 nm之间的吸收归因于d – d跃迁。通过循环伏安法检查复合物的电化学性质。在以下趋势NO 2中，阳极峰值电势更正 > Br> H> MeO，并且根据取代基的电子效应。[Co（5-NO 2 MeSalophen）（PBu 3）（CH 3 OH）] ClO 4和[Co（5-BrMeSalophen）（PPh 3）（CH 3 OH）] ClO 4的晶体结构通过单分子色谱法确定。晶体X射线衍射。他们显示了六坐标伪八面体几何，
• Synthesis, spectroscopy, electrochemistry and thermal study of Ni(II) and Cu(II) unsymmetrical N2O2 Schiff base complexes
  作者：Ali Hossein Kianfar、Liala Keramat、Morteza Dostani、Mojtaba Shamsipur、Mahmoud Roushani、Farzad Nikpour

  DOI：10.1016/j.saa.2010.06.008

  日期：2010.10

  unsymmetrical N2O2 Schiff base ligands, Ni(II) and Cu(II) complexes were synthesised and chracterized by IR, UV–vis, 1H NMR and elemental analysis. The electrochemical properties of the Ni(II) complexes were investigated. The thermogravimetry of the Ni(II) and Cu(II) complexes were carried out in the range of 20–700 °C. Decomposition of synthesised complexes is related to the Schiff base characteristics

  合成了新的四齿不对称N 2 O 2 Schiff碱配体Ni（II）和Cu（II）配合物，并通过IR，UV-vis，1 H NMR和元素分析对其进行了表征。Ni（II）配合物的电化学性质进行了研究。Ni（II）和Cu（II）配合物的热重分析是在20–700°C的范围内进行的。合成配合物的分解与席夫碱特性有关。
• Synthesis, spectroscopy, and thermal study of uranyl unsymmetrical Schiff base complexes
  作者：Ali Hossein Kianfar、Morteza Dostani

  DOI：10.1016/j.saa.2011.06.073

  日期：2011.11

  The new uranyl complexes with tetradentate unsymmetrical N(2)O(2) Schiff base ligands were synthesized and characterized by IR, UV-vis, NMR and elemental analysis. The DMF solvent is coordinated to uranyl complexes. The thermogravimetry (TG) and differential thermoanalysis (DTA) of the uranyl complexes were carried out in the range of 20-700 degrees C. The UO(2)L(1) complex was decomposed in two and the others were decomposed in three stages. Up to 100 degrees C, the coordinated solvent was released then the Schiff base ligands were decomposed in one or two steps. Decomposition of synthesized complexes is related to the Schiff base characteristics. The thermal decomposition reaction is first order for the studied complexes. (C) 2011 Elsevier B.V. All rights reserved.