| 173853-58-2

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• CAS: 173853-58-2
• 化学式: C₄H₆N₆O₄Pd*H₄N
• 分子量: 326.588
• InChiKey: DEBFGDDSUDZSPN-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  ammonium tetrachloropalladate(II) 、 缩二脲 在 KOH 、 O₂ 作用下， 以 水 为溶剂， 以34%的产率得到
  参考文献：
  名称：

  Synthesis of New Monomeric Pd(III) and Dimeric (Pd(III),Pd(II)) Complexes with Biuret Formed in Basic Medium

  摘要：

  New monomeric Pd(III) and dimeric (Pd(III)-Pd(II)) paramagnetic complexes with biuret (BiuH(2)) were synthesized and their structures and coordination modes studied using magnetochemical and spectroscopic (EPR, LR, ESCA) methods. For the monomeric species a metal to ligand ratio 1:2 was found and for the dimeric one it was 2:3. A distorted rhombic structure was suggested for the [Pd(III)(Biu)(2)] species. For the dimeric complex it was accepted that one of the biuret molecules is serving as bridging ligand coordinated via both NH-groups to one of the palladium ions and via both C = O groups to the other. A distorted rhombic structure is suggested for each of the palladium ions.

  DOI：

  10.1080/00945719708000257