K[Fe(8-(pyridine-2-carboxamido)quinoline(1-))(CN)3] | 872971-23-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: K[Fe(8-(pyridine-2-carboxamido)quinoline(1-))(CN)3]
• CAS: 872971-23-8
• 化学式: C₁₈H₁₀FeN₆O*K
• 分子量: 421.262
• InChiKey: ZANXPFASFBASFV-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  dichlorobis(2,2'-bipyridine)manganese(II) 、 K[Fe(8-(pyridine-2-carboxamido)quinoline(1-))(CN)3] 以 not given 为溶剂， 生成 [Fe(8-(pyridine-2-carboxamido)quinoline(1-))(CN)3]2[Mn(bipy)2]*CH3OH*2H2O
  参考文献：
  名称：

  mer-[Fe(pcq)(CN)₃]^-:  A Novel Cyanide-Containing Building Block and Its Application to Assembling Cyanide-Bridged Trinuclear Fe^III₂Mn^II Complexes [pcq^- = 8-(Pyridine-2-carboxamido)quinoline Anion]

  摘要：

  A new cyanide-containing building block K[Fe(pcq)(CN)(3)] [1; pcq(-) = 8-(pyridine-2-carboxamido)quinoline anion] containing a low-spin Fe-III center with three cyanide groups in a meridional arrangement has been successfully designed and synthesized. Three cyanide-bridged trinuclear (Fe2MnII)-Mn-III complexes, [Fe(pcq)(CN)(3)](2)[Mn(CH3OH)(2)(H2O)(2)]center dot 2H(2)O (2), [Fe(pcq)(CN)(3)](2)[Mn(bipy)(2)](center dot) CH3OH center dot 2H(2)O (3), and [Fe(pcq)(CN)(3)](2)[Mn(phen)(2)]center dot CH3OH center dot 2H(2)O (4), have been synthesized and structurally characterized. The magnetic susceptibilities of the three heterometallic complexes have been investigated.

  DOI：

  10.1021/ic051385v