| 1246176-57-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 1246176-57-7
• 化学式: C₂₂H₃₆O₄Si
• 分子量: 392.611
• InChiKey: LOZWNAQMNOKMJN-FNAHDJPLSA-N

反应信息

• 作为反应物：
  描述：

  、 溴甲苯 在 potassium tert-butylate 、 四丁基碘化铵 作用下， 以 四氢呋喃 为溶剂， 生成
  参考文献：
  名称：

  Synthesis of the BC/DE ring model of brevisin for confirmation of the structure around the acyclic junction

  摘要：

  Synthesis of the BC/DE ring model of brevisin, a polycyclic ether isolated from the red tide dinoflagellate Karenia brevis, is reported. Comparison of the NMR data of the BC/DE ring model with those corresponding to the same region of brevisin led to the confirmation of its structure around the acyclic juncture. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2010.07.001
• 作为产物：
  描述：

  在 二异丁基氢化铝 作用下， 以 二氯甲烷 为溶剂， 以67%的产率得到
  参考文献：
  名称：

  Synthesis of the BC/DE ring model of brevisin for confirmation of the structure around the acyclic junction

  摘要：

  Synthesis of the BC/DE ring model of brevisin, a polycyclic ether isolated from the red tide dinoflagellate Karenia brevis, is reported. Comparison of the NMR data of the BC/DE ring model with those corresponding to the same region of brevisin led to the confirmation of its structure around the acyclic juncture. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2010.07.001

文献信息

• Chemoselective deprotection of silyl ethers by DIBALH
  作者：Takefumi Kuranaga、Shuji Ishihara、Naohito Ohtani、Masayuki Satake、Kazuo Tachibana

  DOI：10.1016/j.tetlet.2010.09.126

  日期：2010.12

  The first examples of highly selective deprotection of silyl ethers by DIBALH are reported. Its selectivity enabled us to remove a primary TBS group and a primary TBDPS group in the presence of a secondary TES group. (C) 2010 Elsevier Ltd. All rights reserved.