(R)-2-(bis(trimethylsilyl)amino)-1,3-diisobutyl-2,3-dihydrocyclohepta[d][1,3,2]diazagermol-1-ium | 1609138-23-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (R)-2-(bis(trimethylsilyl)amino)-1,3-diisobutyl-2,3-dihydrocyclohepta[d][1,3,2]diazagermol-1-ium
• CAS: 1609138-23-9
• 化学式: C₂₁H₄₁GeN₃Si₂
• 分子量: 464.338
• InChiKey: CUGODZQFFNAFMY-UHFFFAOYSA-N

物化性质

• 熔点：
  72 °C

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (R)-2-(bis(trimethylsilyl)amino)-1,3-diisobutyl-2,3-dihydrocyclohepta[d][1,3,2]diazagermol-1-ium 以 四氢呋喃 为溶剂， 反应 14.0h， 生成
  参考文献：
  名称：

  Reactivity of LGe–NR₂ and LGe(E)–NR₂ over LGe–Cl and LGe(E)–Cl toward Me₃SiX (L = Aminotroponiminate; NR₂ = N(SiMe₃)₂/NC₄H₄; E = S/Se; X = Br/CN)

  摘要：

  The halogen exchange reaction of either germylene monochloride [LGeCl] (1) or germachalcogenoacid chlorides [LGe(E)Cl] (L = (i-Bu)(2)ATI; ATI = aminotroponiminate; E = S (V)/Se (VI)) with Me3SiX (X = Br/CN) did not occur. Therefore, the reactions of germanium compounds containing Ge-N bonds with Me3SiBr/CN were tried. Germylene amide [LGeN(SiMe3)(2)] (2) reacted with Me3SiBr to afford the aminotroponiminatogermylene monobromide [LGeBr] (3). Similarly, the chalcogen derivatives of compound 2, viz., germachalcogenoamides [LGe-(E)N(SiMe3)(2)] (E = S 4 and Se 5) reacted with Me3SiBr and resulted in germachalcogenoacid bromides [LGe(E)Br] (E = S 6 and Se 7), respectively. N-Germylene pyrrole [LGeNC4H4] (2a) and N-germachalcogenoacylpyrroles [LGe(E)NC4H4] (E = S 4a, Se 5a) also reacted with Me3SiBr and afforded compounds 3, and 6-7 in excellent yields, respectively. Interestingly, the reaction of compound 2a with Me3SiCN afforded germanium(II) cyanide [LGeCN] (8). The difference in the reactivity of compounds (1, V, and VI) with Ge-Cl bonds against the compounds (2, 4, and 5) with Ge-N bonds was analyzed theoretically.

  DOI：

  10.1021/acs.organomet.5b00643
• 作为产物：
  描述：

  [(i-Bu)2(aminotroponiminate)GeCl] 、 lithium hexamethyldisilazane 以 正己烷 为溶剂， 反应 12.5h， 以96%的产率得到(R)-2-(bis(trimethylsilyl)amino)-1,3-diisobutyl-2,3-dihydrocyclohepta[d][1,3,2]diazagermol-1-ium
  参考文献：
  名称：

  Reactivity of LGe–NR₂ and LGe(E)–NR₂ over LGe–Cl and LGe(E)–Cl toward Me₃SiX (L = Aminotroponiminate; NR₂ = N(SiMe₃)₂/NC₄H₄; E = S/Se; X = Br/CN)

  摘要：

  The halogen exchange reaction of either germylene monochloride [LGeCl] (1) or germachalcogenoacid chlorides [LGe(E)Cl] (L = (i-Bu)(2)ATI; ATI = aminotroponiminate; E = S (V)/Se (VI)) with Me3SiX (X = Br/CN) did not occur. Therefore, the reactions of germanium compounds containing Ge-N bonds with Me3SiBr/CN were tried. Germylene amide [LGeN(SiMe3)(2)] (2) reacted with Me3SiBr to afford the aminotroponiminatogermylene monobromide [LGeBr] (3). Similarly, the chalcogen derivatives of compound 2, viz., germachalcogenoamides [LGe-(E)N(SiMe3)(2)] (E = S 4 and Se 5) reacted with Me3SiBr and resulted in germachalcogenoacid bromides [LGe(E)Br] (E = S 6 and Se 7), respectively. N-Germylene pyrrole [LGeNC4H4] (2a) and N-germachalcogenoacylpyrroles [LGe(E)NC4H4] (E = S 4a, Se 5a) also reacted with Me3SiBr and afforded compounds 3, and 6-7 in excellent yields, respectively. Interestingly, the reaction of compound 2a with Me3SiCN afforded germanium(II) cyanide [LGeCN] (8). The difference in the reactivity of compounds (1, V, and VI) with Ge-Cl bonds against the compounds (2, 4, and 5) with Ge-N bonds was analyzed theoretically.

  DOI：

  10.1021/acs.organomet.5b00643

文献信息

• Are Ligand-Stabilized Carboxylic Acid Derivatives with Ge═Te Bonds Isolable?
  作者：Rahul Kumar Siwatch、Dhirendra Yadav、Goutam Mukherjee、Gopalan Rajaraman、Selvarajan Nagendran

  DOI：10.1021/ic500116f

  日期：2014.5.19

  The stability of ligand-stabilized carboxylic acid derivatives (such as esters, amides, anhydrides, and acid halides) with terminal Ge=Te bonds is highly questionable as there is no report on such compounds. Nevertheless, we are able to isolate germatelluroester [LGe(Te)Ot-Bu] (4), germatelluroamide [LGe(Te)N(SiMe3)(2)] (5), and germatelluroacid anhydride [LGe(Te)OGe(Te)L] (6) complexes (L = aminotroponiminate (ATI)) as stable species. Consequently, the synthetic details, structural characterization, and UV-vis spectroscopic and theoretical studies on them are reported for the first time.