[(i-Bu)2(aminotroponiminate)GeCl] | 1370704-80-5

• 英文名称: [(i-Bu)2(aminotroponiminate)GeCl]
• 英文别名: aminotroponiminatogermylene monochloride；[(isobutyl)₂(aminotroponiminate)]GeCl；[(i-Bu)₂(aminotroponiminate)GeCl]；[(i-Bu)₂-aminotroponiminateGeCl]；[(i-Bu)₂aminotroponiminate]GeCl；[(i-Bu)₂ATIGeCl]；[(i-Bu)₂ATI]GeCl
• CAS: 1370704-80-5
• 化学式: C₁₅H₂₃ClGeN₂
• 分子量: 339.404
• InChiKey: IRJQKTKJYWBXBC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  [(i-Bu)2(aminotroponiminate)GeCl] 以 四氢呋喃 、 甲苯 为溶剂， 反应 18.0h， 生成 (i-Bu2ATI)Ge(Se)NC4H4
  参考文献：
  名称：

  Synthesis and Reactivity of N-Aminotroponiminatogermylenepyrrole and Its Derivatives

  摘要：

  Through the reaction of the aminotroponiminatogermylene monochloride complex [(Bu(2)(i)ATI)GeCl] (1) with sodium pyrrolide, the stable N-germylene pyrrole complex [(Bu(2)(i)ATI)GeNC4H4] (2) has been isolated. The reaction of compound 2 with thiophenol and selenophenol afforded the first germylene thio- and selenophenoidde complexes [(Bu(2)(i)ATI)GeSPh] (3) and [(Bu(2)(i)ATI)GeSePh] (4) through the substitution of the pyrrole moiety (NC4H4) with an EPh moiety (E = S (3), Se (4)), respectively. Interestingly, the chalcogenide derivatives of compound 2, such as the N-germathioacylpyrrole complex [(Bu(2)(i)ATI)Ge(S)NC4H4] (5) and N-germaselenoacylpyrrole complex [(Bu(2)(i)ATI)Ge(Se)NC4H4] (6), also underwent the aforementioned substitution reaction with thiophenol and selenophenol, resulting in the first examples of germa thioester complexes ([(Bu(2)(i)ATI)Ge(S)SPh] (7) and [(Bu(2)(i)ATI)Ge(Se)SPh] (8)) and germa selenoester complexes ([(Bu(2)(i)ATI)Ge(S)SePh] (9) and [(Bu(2)(i)ATI)Ge(Se)SePh] (10)), respectively. All the novel germanium compounds 3-10 have been unequivocally characterized through multinuclear NMR spectroscopy along with the germylene complex 2. Further, compounds 3-5 and 7-10 were characterized through single-crystal X-ray diffraction studies. The Ge-II-S and Ge-II-Se bond lengths in compounds 3 and 4 are 2.367(1) and 2.511(1) angstrom, respectively. The average Ge-IV-S and Ge-IV-Se bond lengths in germa thioester (7 and 8) and germa selenoester (9 and 10) complexes are 2.241(1) and 2.362(1) angstrom, respectively.

  DOI：

  10.1021/om4003158

文献信息

• Ge(<scp>ii</scp>) cation catalyzed hydroboration of aldehydes and ketones
  作者：Soumen Sinhababu、Dharmendra Singh、Mahendra Kumar Sharma、Rahul Kumar Siwatch、Pritam Mahawar、Selvarajan Nagendran

  DOI：10.1039/c8dt05121f

  日期：——

  Well-defined germylene cations [(i-Bu)2ATI]GeOTf (4) and [(i-Bu)2ATIGe][GaCl4] (5) are isolated, and the catalytic utility of compound 4 for the hydroboration of a variety of aldehydes and ketones is reported (ATI = aminotroponiminate).

  明确定义的亚甲锗阳离子[（我-Bu）2 ATI] GeOTf（4）和[（我-Bu）2 ATIGe] [的GaCl 4 ]（5）是分离的，并且化合物的催化效用4为一个的硼氢化据报道，醛和酮的种类繁多（ATI =氨基苯甲酸酯）。
• Reactivity studies on aminotroponiminatogermylene stabilized ruthenium(II) complexes
  作者：Dhirendra Yadav、Dharmendra Singh、Debotra Sarkar、Soumen Sinhababu、Mahendra Kumar Sharma、Selvarajan Nagendran

  DOI：10.1016/j.jorganchem.2019.02.006

  日期：2019.6

  stabilized ruthenium(II) complexes and reactivity studies on N-heterocyclic germylene stabilized ruthenium(II) complexes were not known. Therefore, this work reports the synthesis of aminotroponiminatogermylene stabilized ruthenium(II) complexes [L1Ge(X)RuCl2(Y)}] (L1 = (i-Bu)2ATI; (ATI = aminotroponiminate), X = Cl 1, NC4H4 2, Y = η6-p-cymene), and the reactivity studies on complex 2. N-pyrrolylgermylene

  氨基对苯二甲酰氨基亚锗烷稳定的钌（II）配合物和N-杂环亚甲基苯撑稳定的钌（II）配合物的反应性研究尚不清楚。因此，这项工作报告了氨基对苯二甲酰氨基亚锗烷稳定的钌（II）配合物的合成[L 1 Ge（X）RuCl 2（Y）}]（L 1  =（i -Bu）2 ATI；（ATI =氨基对苯二甲酸酯），X = CL 1，NC 4 ħ 4 2，Y =  η 6 - p -cymene），并且在复合物中的反应性研究2。N-吡咯基亚甲基稳定的钌（II）配合物2分发生反应用H 2 O和的SnCl 2，得到hydroxygermylene稳定钌（II）络合物[L 1的Ge（OH）的RuCl 2（Y）}]（3）和一个双金属络合物[L 1葛（NC 4 H ^ 4） Ru（SnCl 3）Cl（Y）}]（4）。所述chlorogermylene类似物[L 1 GeCl 茹（的SnCl 3）氯（Y）}]（5）
• Donor–acceptor-stabilised germanium analogues of acid chloride, ester, and acyl pyrrole compounds: synthesis and reactivity
  作者：Mahendra Kumar Sharma、Soumen Sinhababu、Pritam Mahawar、Goutam Mukherjee、Bhawana Pandey、Gopalan Rajaraman、Selvarajan Nagendran

  DOI：10.1039/c8sc05380d

  日期：——

  Germaacid chloride, germaester, and N-germaacyl pyrrole compounds were not known previously. Therefore, donor–acceptor-stabilised germaacid chloride (i-Bu)2ATIGe(O)(Cl) → B(C6F5)3 (1), germaester (i-Bu)2ATIGe(O)(OSiPh3) → B(C6F5)3 (2), and N-germaacyl pyrrole (i-Bu)2ATIGe(O)(NC4H4) → B(C6F5)3 (3) compounds, with Cl–GeO, Ph3SiO–GeO, and C4H4N–GeO moieties, respectively, are reported here. Germaacid

  Germaacid chloride、germaester 和N -germaacyl pyrrole 化合物以前是未知的。因此，供体-受体稳定的锗酰氯 (i-Bu) 2 ATIGe(O)(Cl) → B(C 6 F 5 ) 3 ( 1 ), Germaester (i-Bu) 2 ATIGe(O)(OSiPh 3 ) → B(C 6 F 5 ) 3 ( 2 ) 和N -germaacyl pyrrole (i-Bu) 2 ATIGe(O)(NC 4 H 4 ) → B(C 6 F 5 ) 3 ( 3 ) 化合物，含 Cl ——锗这里分别报道了O、Ph 3 SiO-Ge O 和 C 4 H 4 N-Ge O 部分。Germaacid chloride 1与 PhCCLi、KO t -Bu和 RLi (R = Ph, Me) 反应得到供体-受体稳定的 Germaynone (i-Bu) 2 ATIGe(O)(CCPh)
• Aminotroponiminatogermaacid Halides with a Ge(E)X Moiety (E = S, Se; X = F, Cl)
  作者：Soumen Sinhababu、Rahul Kumar Siwatch、Goutam Mukherjee、Gopalan Rajaraman、Selvarajan Nagendran

  DOI：10.1021/ic300715y

  日期：2012.9.3

  13 ppm) resonances in their 77Se NMR spectra, respectively. Germylene monohalide complexes 2 and 9 have a germanium center in distorted trigonal pyramidal geometry, whereas a distorted tetrahedral geometry is seen around the germanium center in germaacid halide complexes 4, 11, and 12. The length of the Ge═E bond in germathioacid chloride (11) and germaselenoacid halide (4 and 12) complexes is 2.065(1)

  用CsF氟化对氨基苯甲酸亚胺（ATI）配体稳定的亚二氯单氯化物[（t -Bu）2 ATI] GeCl（1），得到了氨基对苯二甲酰氨基香格里气单氟化物[（t -Bu ）2 ATI] GeF（2）。化合物2与元素硫和硒的氧化加成反应导致分离出相应的杀菌硫代酸氟化物[（t -Bu ）2 ATI] Ge（S）F（3）和胚芽烯酸氟[[ t -Bu ）2 ATI] Ge（ Se）F（4）。类似地，氨基托苯那氨基合一二氯甲烷[（i -Bu ）的反应2含元素硫和硒的ATI] GeCl（9）得到了氨基对苯二甲氨基锗金属硫酰氯[（i -Bu ）2 ATI] Ge（S）Cl（11）和氨基对苯二甲氨基锗金属硒酸氯[（i -Bu ）2 ATI] Ge（Se）Cl （12）。化合物9已经通过多步合成路线从2-（甲苯磺酰氧基）托酮5开始制备。所有化合物（2 - 4和6 - 12）通过多核NMR光谱进行了表征，并在化合物进行单晶X射线衍射研究2，4，和8
• Pseudohalogenogermylenes versus Halogenogermylenes: Difference in their Complexation Behavior towards Group 6 Metal Carbonyls
  作者：Mahendra Kumar Sharma、Soumen Sinhababu、Dhirendra Yadav、Goutam Mukherjee、Gopalan Rajaraman、Selvarajan Nagendran

  DOI：10.1002/asia.201800248

  日期：2018.5.18

  coordination behavior towards group 6 metal carbonyls in comparison to the corresponding halogenogermylenes [(iBu)2ATI]GeX (X=F 1, Cl 2, Br 3) (ATI=aminotroponiminate). The reactions of compounds 4–5 and 1–3 with cis‐[M(CO)4(COD)] (M=Mo, W, COD=cyclooctadiene) gave trans‐germylene metal complexes [(iBu)2ATI]GeY}2M(CO)4 (Y=NCO, M=Mo 6, W 11; Y=NCS, M=Mo 7) and cis‐germylene metal complexes [(iBu)2ATI]GeX}2M(CO)4

  伪卤化亚germylene [[ i Bu）2 ATI] GeY（Y = NCO 4，NCS 5）与相应的卤化亚锗烯[（i Bu）2 ATI] GeX（X = F 1，Cl 2，Br 3）（ATI =氨基对苯二甲酸酯）。化合物4 – 5和1 – 3与顺式[[M（CO）4（COD）]（M = Mo，W，COD =环辛二烯）的反应得到反式-亚锗金属配合物[（i Bu）2ATI] GeY} 2 M（CO）4（Y = NCO，M = Mo 6，W 11 ; Y = NCS，M = Mo 7）和顺式锗金属配合物[（i Bu）2 ATI] GeX} 2 M（CO）4（M ＝ Mo，X ＝ F 8，Cl 9，Br 10； M ＝ W，X ＝ Cl 12）。上化合物的理论研究 7和9揭示选自Mo到Ge原子供体-受体相互作用中所观察到的被更好地稳定的反式与顺式的几何形状比假想顺和反式结构。