N,N,N'-triphenyl-N'-(4-((4-vinylphenyl)methoxymethyl)phenyl)-p-phenylenediamine | 849146-81-2

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N,N,N'-triphenyl-N'-(4-((4-vinylphenyl)methoxymethyl)phenyl)-p-phenylenediamine
• 英文别名: 4-N-[4-[(4-ethenylphenyl)methoxymethyl]phenyl]-1-N,1-N,4-N-triphenylbenzene-1,4-diamine
• CAS: 849146-81-2
• 化学式: C₄₀H₃₄N₂O
• 分子量: 558.723
• InChiKey: ZFAHRVBUFBKPEK-UHFFFAOYSA-N

物化性质

• 沸点：
  704.9±60.0 °C(Predicted)
• 密度：
  1.169±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  10.3
• 重原子数：
  43
• 可旋转键数：
  11
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  15.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  4-溴三苯胺 在 tris(dibenzylideneacetone)dipalladium (0) 1,1'-双(二苯基膦)二茂铁 、 三叔丁基膦 、 四丁基氟化铵 、 氢化钾 、 sodium t-butanolate 作用下， 以 四氢呋喃 、 水 、 甲苯 为溶剂， 反应 36.0h， 生成 N,N,N'-triphenyl-N'-(4-((4-vinylphenyl)methoxymethyl)phenyl)-p-phenylenediamine
  参考文献：
  名称：

  Synthesis and Characterization of Photo-Cross-Linkable Hole-Conducting Polymers

  摘要：

  The synthesis and characterization of side-chain polymers functionalized with hole-transporting units and photo-cross-linkable groups, which can be used for solution-based preparation of multilayer organic light-emitting devices (OLEDs), are discussed. The concept deals with triarylamine and oxetane-functionalized styrenes, which are copolymerized by radical polymerization. Four different types of hole-transporting monomers were combined with one cross-linkable monomer in two different ratios, yielding two groups of each four polymers (P1A...P4A and P1B...P4B). The polymers were investigated by NMR spectroscopy, molecular weights were determined by GPC with light scattering, and the thermal properties were measured with differential scanning calorimetry (DSC). Optical characterization by UV-vis and fluorescence spectroscopy was performed. Electrochemical and cross-linking characteristics of the copolymers were investigated to proove this strategy's potential in application for modern multilayer polymer OLEDs. Finally, hole-only devices were prepared for evaluation of the semiconductive performance of the materials.

  DOI：

  10.1021/ma048365h

文献信息

• Synthesis and Characterization of Photo-Cross-Linkable Hole-Conducting Polymers
  作者：Erwin Bacher、Michael Bayerl、Paula Rudati、Nina Reckefuss、C. David Müller、Klaus Meerholz、Oskar Nuyken

  DOI：10.1021/ma048365h

  日期：2005.3.1

  The synthesis and characterization of side-chain polymers functionalized with hole-transporting units and photo-cross-linkable groups, which can be used for solution-based preparation of multilayer organic light-emitting devices (OLEDs), are discussed. The concept deals with triarylamine and oxetane-functionalized styrenes, which are copolymerized by radical polymerization. Four different types of hole-transporting monomers were combined with one cross-linkable monomer in two different ratios, yielding two groups of each four polymers (P1A...P4A and P1B...P4B). The polymers were investigated by NMR spectroscopy, molecular weights were determined by GPC with light scattering, and the thermal properties were measured with differential scanning calorimetry (DSC). Optical characterization by UV-vis and fluorescence spectroscopy was performed. Electrochemical and cross-linking characteristics of the copolymers were investigated to proove this strategy's potential in application for modern multilayer polymer OLEDs. Finally, hole-only devices were prepared for evaluation of the semiconductive performance of the materials.