1-(allyloxy)-4-methyl-2,6-divinylbenzene | 1228276-16-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 1-(allyloxy)-4-methyl-2,6-divinylbenzene
• CAS: 1228276-16-1
• 化学式: C₁₄H₁₆O
• 分子量: 200.28
• InChiKey: QPWXIKNIQRLBFU-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  1-(allyloxy)-4-methyl-2,6-divinylbenzene 在 Grubbs catalyst first generation 作用下， 以 二氯甲烷 为溶剂， 反应 5.0h， 以95%的产率得到6-methyl-8-vinyl-2H-chrom-3-ene
  参考文献：
  名称：

  New efficient ruthenium metathesis catalyst containing chromenyl ligand

  摘要：

  A synthesis of new Hoveyda-Grubbs-type catalyst with chromenyl ligand was described herein. The new catalyst was tested in model RCM and CM reactions. The catalyst proved to be quite efficient. It showed activity comparable or superior to that of commercially available Grubbs second-generation complexes. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2010.02.025
• 作为产物：
  描述：

  3-溴丙烯 、 4-methyl-2,6-divinylphenol 在 18-冠醚-6 、 potassium carbonate 作用下， 以 丙酮 为溶剂， 反应 1.0h， 以98%的产率得到1-(allyloxy)-4-methyl-2,6-divinylbenzene
  参考文献：
  名称：

  New efficient ruthenium metathesis catalyst containing chromenyl ligand

  摘要：

  A synthesis of new Hoveyda-Grubbs-type catalyst with chromenyl ligand was described herein. The new catalyst was tested in model RCM and CM reactions. The catalyst proved to be quite efficient. It showed activity comparable or superior to that of commercially available Grubbs second-generation complexes. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2010.02.025