[Nd(2,3,4-trimethoxybenzoate)3] | 262586-51-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: [Nd(2,3,4-trimethoxybenzoate)3]
• CAS: 262586-51-6
• 化学式: C₃₀H₃₃NdO₁₅
• 分子量: 777.823
• InChiKey: XILUPYYFADPYPH-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Nd(2,3,4-trimethoxybenzoate)3] 在 air 作用下， 以 solid 为溶剂， 生成 neodymium(III) oxide
  参考文献：
  名称：

  摘要：

  The physico-chemical properties and thermal stability in air of light lanthanide 2,3,4-, 2,4,5- and 3,4,5-trimethoxybenzoates were compared and the influence of the position of -OCH3 substituent on their thermal stability was investigated. The complexes of these series are crystalline, hydrated or anhydrous salts with colours typical of Ln(3)+ ions. The carboxylate group is a bidentate, chelating ligand. The thermal stability of 2,3,4-, 2,4,5- and 3,4,5-trimethoxybenzoates of rare earth elements was studied in the temperature range 273-1173 K. The positions of methoxy groups in benzene ring influence the thermal properties of the complexes and their decomposition mechanism. The different thermal properties of the complexes are connected with various influence of inductive and mesomeric effects of -OCH3 substituent on the electron density in benzene ring.

  DOI：

  10.1023/a:1010188905767
• 作为产物：
  描述：

  ammonium 2,3,4-trimethoxybenzoate 、 neodymium(III) nitrate 以 水 为溶剂， 生成 [Nd(2,3,4-trimethoxybenzoate)3]
  参考文献：
  名称：

  摘要：

  The physico-chemical properties and thermal stability in air of light lanthanide 2,3,4-, 2,4,5- and 3,4,5-trimethoxybenzoates were compared and the influence of the position of -OCH3 substituent on their thermal stability was investigated. The complexes of these series are crystalline, hydrated or anhydrous salts with colours typical of Ln(3)+ ions. The carboxylate group is a bidentate, chelating ligand. The thermal stability of 2,3,4-, 2,4,5- and 3,4,5-trimethoxybenzoates of rare earth elements was studied in the temperature range 273-1173 K. The positions of methoxy groups in benzene ring influence the thermal properties of the complexes and their decomposition mechanism. The different thermal properties of the complexes are connected with various influence of inductive and mesomeric effects of -OCH3 substituent on the electron density in benzene ring.

  DOI：

  10.1023/a:1010188905767