| 1350883-85-0

• 分子结构分类: 有机化合物 - 有机杂环化合物
• CAS: 1350883-85-0
• 化学式: C₄₄H₃₄N₆O₈Pd₂
• 分子量: 987.629
• InChiKey: FTBLLQVUKVMRSN-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  palladium diacetate 、 1-p-nitrophenylimino-2-phenylisoindoline 以 二氯甲烷 为溶剂， 以27%的产率得到
  参考文献：
  名称：

  Synthesis of mixed N,N′-(Ar,Ar′-diaryl)iminoisoindolines for applications in palladacycle formations

  摘要：

  The synthesis of N,N'-(Ar,Ar'-diaryl)iminoisoindolines containing different aryl groups bound to the two nitrogen atoms is described. The iminoisoindolines were obtained by a three component, one-pot reaction of phthalaldehyde with 1 equivalent p-NO2-aniline and 1 equivalent p-R-aniline, where R = H, Me, MeO or Pr-i, resulting in formation of non-symmetrically substituted (mixed) iminoisoindolines, 1-p-nitrophenylimino-2-p-R-phenylisoindoline (R = H (1), Me (2), MeO (3), and Pr-i (4)), as analytically pure precipitates requiring no further purification. Only one isomer precipitates from solution wherein the nitro group resides exclusively at the imine position while the more electron donating substituent ends up on the isoindoline ring position. Further reaction with Pd(OAc)(2) in dichloromethane at room temperature results in formation of six-membered [C,N] dinuclear cyclopalladated complexes with the general formula [(Ar,Ar'-diaryliminoisoindoline)Pd{mu-OAc}](2). (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.09.054