4'-carbazol-9-yl-2,2':6',2''-terpyridine | 1225026-49-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 4'-carbazol-9-yl-2,2':6',2''-terpyridine
• 英文别名: 4'-(9H-carbazol-9yl)2,2':6',2''-terpyridine；9-(2,6-dipyridyl-pyridin-4-yl)carbazole；9-(2,6-Dipyridin-2-ylpyridin-4-yl)carbazole
• CAS: 1225026-49-2
• 化学式: C₂₇H₁₈N₄
• 分子量: 398.467
• InChiKey: BRDAQGCAQGKFTD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.2
• 重原子数：
  31
• 可旋转键数：
  3
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  43.6
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  4'-carbazol-9-yl-2,2':6',2''-terpyridine 、 Eu(dbm)₃·2H₂O 以 乙醇 为溶剂， 以21.4%的产率得到tris(dibenzoylmethanido)-(4'-(9H-carbazol-9yl)2,2':6',2''-terpyridine) europium
  参考文献：
  名称：

  Synthesis and photoluminescence properties of heteroleptic Eu3+, Tb3+ and Tm3+ complexes

  摘要：

  Five Eu(III), four Tb(III) and two Tm(III) multichromophoric complexes (1-Eu, 1-Th, 2-Eu, 3-Eu, 3-Th, 3-Tm. 4-7b, 4-Tm, 5-Eu. 6-Eu and 6-Th: where 1 = tris[dibenzoylmethanido] (4'-chloro-2,2'-6',2 ''-terpyndine), 2 = tris[dibenzoylmethanido] (4'-(9H-carbazol-9yl)-2.2':6'.2 ''-terpyridine), 3 = tris(1.1,1.5.5.5-hexafluoroacetylacetonato), 4 = tris[1,1,5,5,5-hexafluoroacetylacetonato] (tripyridin-2-ylamine), 5 = tris[dibenzoylmethanido][N-(4-(9H-carbazol-9-yl)butyl)-N-(dipyridin-2-yl)amine] and 6 = tris[dibenzoylmethanido][N-(6-(9H-carbazol-9-yl)hexyl)-N-(dipyridin-2-yl)amine]) emitting in the blue (Tm), green (Tb) and red (Eu) spectral regions, have been synthesized and characterized. The complexes involve five different coordinating (2.2':6'.2 ''-terpyridine (terpy): dibenzoylmethane (dbm); 1,1,1,5,5,5-hexafluoroacetylacetonato (hfa), tripyridin-2-ylamine (tri-amine) and N-(dipyridin-2-yl)amine (di-amine)) and one non-coordinating (carbazole) units. The synthesis and photophysical properties of these complexes are reported addressing the influence of the various ligands on the lanthanide metal-centered luminescence in CH2Cl2 solution and solid state matrices. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jallcom.2009.06.096

文献信息

• Synthesis and photoluminescence properties of rhenium(<scp>i</scp>) complexes based on 2,2′:6′,2′′-terpyridine derivatives with hole-transporting units
  作者：Dong Wang、Qiu-Lei Xu、Song Zhang、Hong-Yan Li、Cheng-Cheng Wang、Tian-Yi Li、Yi-Ming Jing、Wei Huang、You-Xuan Zheng、Gianluca Accorsi

  DOI：10.1039/c2dt32154h

  日期：——

  Based on 2,2′:6′,2′′-terpyridine ligands (L1), five terpyridine derivatives, namely 4′-carbazol-9-yl-2,2′:6′,2′′-terpyridine (L2), 4′-diphenylamino-2,2′:6′,2′′-terpyridine (L3), 4′-bis(4-tert-butylphenyl)amino-2,2′:6′,2′′-terpyridine (L4), 4′-[naphthalen-1-yl-(phenyl)amino]-2,2′:6′,2′′-terpyridine (L5), 4′-[naphthalen-2-yl(phenyl)amino]-2,2′:6′,2′′-terpyridine (L6) and their corresponding Re(I) complexes

  基于2,2'：6'，2''-吡啶吡啶配体（L1），五种吡啶吡啶衍生物，即4'-咔唑-9-yl-2,2'：6'，2''-吡啶吡啶（L2） ，4'-二苯基氨基-2,2'：6'，2''-吡啶（L3），4'-双（4-叔丁基苯基）氨基-2,2'：6'，2''-吡啶（L4），4'-[萘-1-基-（苯基）氨基] -2,2'：6'，2''-吡啶（L5），4'-[萘-2-基（苯基）氨基] -2,2'：6'，2''-吡啶（L6）及其相应的Re（I）配合物ReL n n n（CO）3 3Cl（n = 1-6）已被合成并通过元素分析和表征1个1 H NMR光谱。还获得了ReL3（CO）3 3Cl的X射线晶体结构。在室温下在CH 2 Cl 2溶液中获得的ReL2（CO）3 3Cl–ReL5（CO）3 3Cl的发光光谱显示出很强的dπ（Re）→π*（二亚胺）MLCT字符（λ最大〜600纳米），并相对于一个小的红移REL1（CO）3
• Material for organic electroluminescent devices and organic electroluminescent devices made by using the same
  申请人：Iwakuma Toshihiro

  公开号：US20050127823A1

  公开（公告）日：2005-06-16

  A material for electroluminescent devices which comprises a compound in which a heterocyclic group having nitrogen is bonded to carbazolyl group and an organic electroluminescent device having at least one organic thin film layer which is sandwiched between the cathode and the anode and contains the above material in at least one layer, are provided. The material can provide organic electroluminescent devices emitting bluish light with a high purity of color. The organic electroluminescence device uses the material.

  提供了一种用于电致发光装置的材料，其中包括一种化合物，其中含有氮的杂环基与卡巴索基基团结合，并且至少包含一层上述材料的有机薄膜层被夹在阴极和阳极之间的有机电致发光装置。该材料能够提供发射高纯度蓝色光的有机电致发光装置。该有机电致发光装置使用该材料。
• Organic light-emitting compound and organic electroluminescent device using same
  申请人：DOOSAN CORPORATION

  公开号：US10038146B2

  公开（公告）日：2018-07-31

  The present invention relates to a novel indole-based compound having superior hole injection and transport capabilities, light-emitting capabilities, and the like, and an organic electroluminescent device which comprises the indole-based compound in one or more organic layers thereof so as to thereby achieve improved characteristics, such as light-emitting efficiency, driving voltage, and lifespan characteristics.

  本发明涉及一种新型吲哚基化合物，该化合物具有优异的空穴注入和传输能力、发光能力等，还涉及一种有机电致发光器件，该器件在其一个或多个有机层中包含该吲哚基化合物，从而获得更好的特性，如发光效率、驱动电压和寿命特性。
• MATERIAL FOR ORGANIC ELECTROLUMINESCENT DEVICES AND ORGANIC ELECTROLUMINESCENT DEVICES MADE BY USING THE SAME
  申请人：IDEMITSU KOSAN CO., LTD.

  公开号：EP1486550B1

  公开（公告）日：2014-05-21
• Materical for organic electroluminescent devices and organic electroluminescent devices made by using the same
  申请人：Iwakuma Toshihiro

  公开号：US20110309338A1

  公开（公告）日：2011-12-22

  A material for electroluminescent devices which comprises a compound in which a heterocyclic group having nitrogen is bonded to carbazolyl group and an organic electroluminescent device having at least one organic thin film layer which is sandwiched between the cathode and the anode and contains the above material in at least one layer, are provided. The material can provide organic electroluminescent devices emitting bluish light with a high purity of color. The organic electroluminescence device uses the material.