N-(4'-butyrylidene-3'-methyl-1'-phenyl-2'-pyrazolin-5'-one)-o-phenitidine | 385827-13-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: N-(4'-butyrylidene-3'-methyl-1'-phenyl-2'-pyrazolin-5'-one)-o-phenitidine
• CAS: 385827-13-4
• 化学式: C₂₂H₂₅N₃O₂
• 分子量: 363.459
• InChiKey: VZXBSGAHVHOHNT-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  hexaammonium heptamolybdate tetrahydrate 、 N-(4'-butyrylidene-3'-methyl-1'-phenyl-2'-pyrazolin-5'-one)-o-phenitidine 、 盐酸羟胺 以 乙醇 、 N,N-二甲基甲酰胺 为溶剂， 以50%的产率得到dinitrosylbis(N-(4'-butyrylidene-3'-methyl-1'-phenyl-2'-pyrazolin-5'-one)-o-phenitidine(1-))molybdenum(0) monohydrate
  参考文献：
  名称：

  DINITROSYLMOLYBDENUM(0) COMPLEXES OF CATALYTIC AND ENVIRONMENTAL RELEVANCE: A NOVEL SINGLE-STEP SYNTHESIS OF DINITROSYLMOLYBDENUM(0) COMPLEXES OF {Mo(NO)₂}⁶ELECTRON CONFIGURATION INVOLVING CHELATING LIGANDS DIRECTLY FROM MOLYBDATE(VI) AND THEIR CHARACTERIZATION

  摘要：

  This paper reports the synthesis of a new series of novel hexa-oordinated, mixed-ligand dinitrosyl complexes of molybdenum(0) of the compositions [Mo(NO)(2)(L')(2)].H2O {where HL' = 4-butyryl-3-methyl-1-phenyl-2-pyrazoline-5- one (HL1) N-(4'-butyrylidene-3'-methyl-1'-phenyl-2'-pyrazolin-5'-one)-o-phenitidine (HL2) or N(4'-buryrylidene-3'-methyl-1'-phenyl-2'-pyrazolin-5'-one)-p-anisidine (HL3)}, [Mo(NO)(2)(L-4)].H2O {where H2L5=N,N-(4'-buryrylidene-3'-methyl-1'-phenyl-2'-pyrazolin-5'-one)-m-phenylenediamine) in a single step directly from molybdate(VI). The resulting chelates, which have been characterized by elemental analyses, molar conductance, decomposition temperature, magnetic measurements, H-1 NMR, IR, and electronic spectral studies, and were found to contain low-spin Mo(0).

  DOI：

  10.1081/sim-120003206