catena-poly[[diiodozinc(II)]-μ-4,4'-bipyridine-κ(2)N:N'] | 55351-97-8

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: catena-poly[[diiodozinc(II)]-μ-4,4'-bipyridine-κ(2)N:N']
• CAS: 55351-97-8
• 化学式: C₁₀H₈I₂N₂Zn
• 分子量: 475.386
• InChiKey: IYSPKXJGMYESFP-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  4,4'-联吡啶 、 zinc(II) iodide 以 水 为溶剂， 以23.2%的产率得到catena-poly[[diiodozinc(II)]-μ-4,4'-bipyridine-κ(2)N:N']
  参考文献：
  名称：

  catena-Poly[[diiodozinc(II)]-μ-4,4′-bipyridine-κ²N:N′]

  摘要：

  The title compound, [ ZnI2( bipy)] n ( bipy is 4,4'-bipyridine, C10H8N2), has been prepared by the hydrothermal reaction of ZnI2 and bipy at 433 K. Each Zn atom is coordinated by two N atoms from two different bipy ligands and by two I atoms in a distorted tetrahedral geometry, with Zn - N distances ranging from 2.068 ( 7) to 2.101 ( 8) angstrom and Zn - I distances ranging from 2.5471 ( 13) to 2.5673 ( 13) angstrom. The molecular structure features a zigzag polymeric chain. Face- to- face pi-pi stacking interactions between adjacent bipy ligands stabilize the structure.

  DOI：

  10.1107/s0108270106039965