[Cu(NCO)2(N,N-dimethylethylenediamine)]2 | 132903-39-0

• 英文名称: [Cu(NCO)2(N,N-dimethylethylenediamine)]2
• CAS: 132903-39-0
• 化学式: C₁₂H₂₄Cu₂N₈O₄
• 分子量: 471.466
• InChiKey: BOFGFHGACNNROQ-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  [Cu(NCO)2(N,N-dimethylethylenediamine)]2 以 neat (no solvent) 为溶剂， 生成 copper(II) oxide
  参考文献：
  名称：

  摘要：

  Pseudohalide complexes of copper(II) with aliphatic bidentate amines, [Cu(N-3)(2)(N,N-diEten)](2) 1, [Cu(NCO)(2)(N,N-diEten)](2) 2, [Cu(NCO)(2)(N,N-diMeen)](2) 3, [Cu(N-3)(NCS)(N,N'-diMeen)](2) 4 and [Cu(N-3)(NCO)(N,N-diMeen)](2) 5 (N,N-diEten=N,N-diethylethylenediamine; N,N-diMeen=N,N- dimethyl-ethylenediamine and N,N'-diMeen = N,N'-dimethylethylenediamine), were prepared, characterized and their thermal behavior was investigated by TG curves. According to thermal analysis and X-ray diffraction patterns all compounds decomposed giving copper(II) oxide as final product. The mechanisms of decomposition were proposed and an order of thermal stability was established.

  DOI：

  10.1023/a:1019947420249