Glutarsaeure-pentylester | 93691-94-2

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: Glutarsaeure-pentylester
• 英文别名: 5-Oxo-5-pentoxypentanoic acid
• CAS: 93691-94-2
• 化学式: C₁₀H₁₈O₄
• 分子量: 202.251
• InChiKey: RCXRQQYEVFEVKN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.7
• 重原子数：
  14
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  63.6
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  乙酸乙烯酯 、 Glutarsaeure-pentylester 在 硫酸 、 mercury(II) diacetate 、 对苯二酚 作用下， 生成 Glutarsaeure-pentylester-vinylester
  参考文献：
  名称：

  Freidlin,G.N. et al., Journal of general chemistry of the USSR, 1963, vol. 33, p. 919 - 922

  摘要：

  DOI：
• 作为产物：
  描述：

  戊二酸 、 戊醇 生成 Glutarsaeure-pentylester
  参考文献：
  名称：

  Freidlin,G.N. et al., Journal of general chemistry of the USSR, 1963, vol. 33, p. 919 - 922

  摘要：

  DOI：

文献信息

• POLYMERIZABLE COMPOUND, POLYMERIZABLE COMPOSITION, POLYMER, OPTICALLY ANISOTROPIC BODY, AND METHOD FOR PRODUCING POLYMERIZABLE COMPOUND
  申请人：ZEON CORPORATION

  公开号：US20150175564A1

  公开（公告）日：2015-06-25

  A polymerizable compound has a practical low melting point, excellent solubility in a general-purpose solvent, and can produce an optical film at low cost, exhibits low reflected luminance, and achieves uniform conversion of polarized light over a wide wavelength band, an optically anisotropic article. A carbonyl compound is useful as a raw material for producing the polymerizable compound. (In the formula (I), Y 1 to Y 8 represent —C(═O)—O—, G 1 and G 2 represent a C 1-20 divalent linear aliphatic group, Z 1 and Z 2 represent a C 2-10 alkenyl group that is unsubstituted, or substituted with a halogen atom, A x represents a C 2-30 organic group with at least one aromatic ring, A y represents a hydrogen atom or C 1-20 alkyl group, A 1 represents a trivalent aromatic group, A 2 and A 3 represent a C 3-30 divalent alicyclic hydrocarbon group, A 4 and A 5 represent a C 6-30 divalent aromatic group or the like, and Q 1 represents a hydrogen atom.)

  一种可聚合的化合物具有实用的低熔点、在通用溶剂中良好的溶解性，并且可以以低成本制备光学薄膜，表现出较低的反射亮度，并且在宽波长范围内实现偏振光的均匀转换，是一种光学各向异性材料。一种羰基化合物可作为制备可聚合化合物的原料。（在式（I）中，Y1至Y8代表—C(═O)—O—，G1和G2代表C1-20二价线性脂肪族基团，Z1和Z2代表未取代或取代有卤素原子的C2-10烯基基团，Ax代表至少具有一个芳香环的C2-30有机基团，Ay代表氢原子或C1-20烷基基团，A1代表三价芳香族基团，A2和A3代表C3-30二价脂环碳氢基团，A4和A5代表C6-30二价芳香族基团或类似物，Q1代表氢原子。）
• POLYMERIZABLE COMPOUND, POLYMERIZABLE COMPOSITION, POLYMER, AND OPTICALLY ANISOTROPIC PRODUCT
  申请人：ZEON CORPORATION

  公开号：US20160257659A1

  公开（公告）日：2016-09-08

  This invention provides a polymerizable compound represented by formula (I), a polymerizable composition containing the polymerizable compound and a polymerization initiator, a polymer produced by polymerizing the polymerizable compound or the polymerizable composition, and an optically anisotropic product comprising the polymer as a constituent material. In formula (1), Y 1 to Y 9 represent —O—, —S—, —O—C(═O)—, —C(═O)—O— or the like, G 1 and G 2 represent a divalent linear aliphatic group having 1 to 20 carbon atoms or the like, Z 1 to Z 3 represent an alkenyl group having 2 to 10 carbon atoms or the like, A x represents a group represented by a formula (II), wherein X represents an oxygen atom, a sulfur atom or the like, D represents an alkylene group having 1 to 20 carbon atoms or the like, A 1 represents a trivalent aromatic group or the like, A 2 and A 3 represent a divalent alicyclic hydrocarbon group having 3 to 30 carbon atoms or the like, A 4 and A 5 represent a divalent aromatic group having 4 to 30 carbon atoms or the like, Q 1 represents an alkyl group having 1 to 6 carbon atoms or the like, and m and n are 0 or 1.

  这项发明提供了一种可聚合化合物，其表示为式(I)，一种含有该可聚合化合物和聚合引发剂的可聚合组合物，通过聚合该可聚合化合物或可聚合组合物而制备的聚合物，以及作为构成材料的聚合物的光学各向异性产品。在式(1)中，Y1至Y9代表—O—、—S—、—O—C(═O)—、—C(═O)—O—或类似物，G1和G2代表具有1至20个碳原子的双价直链脂肪族基或类似物，Z1至Z3代表具有2至10个碳原子的烯基基团或类似物，Ax代表由式(II)表示的基团，其中X代表氧原子、硫原子或类似物，D代表具有1至20个碳原子的烷基基团或类似物，A1代表三价芳香族基或类似物，A2和A3代表具有3至30个碳原子的双价脂环烃基或类似物，A4和A5代表具有4至30个碳原子的双价芳香族基或类似物，Q1代表具有1至6个碳原子的烷基基团或类似物，m和n为0或1。
• Dihydropyridines
  申请人：Pfizer Limited

  公开号：EP0290211B1

  公开（公告）日：1991-09-04
• DIHYDROXY LACTAM BASED POLYMERS, COMPOSITIONS AND APPLICATIONS THEREOF
  申请人：ISP Investments LLC

  公开号：EP3914635A1

  公开（公告）日：2021-12-01
• PHASE DIFFERENCE PLATE, CIRCULARLY POLARIZING PLATE, AND IMAGE DISPLAY DEVICE
  申请人：ZEON CORPORATION

  公开号：US20150277010A1

  公开（公告）日：2015-10-01

  A phase difference plate including an optically anisotropic layer obtained by curing a composition (A) containing a polymerizable liquid crystal compound with reverse wavelength dispersion and a polymerizable monomer, wherein the polymerizable liquid crystal compound with reverse wavelength dispersion has a main chain mesogen and a side chain mesogen bonded to the main chain mesogen in the molecule thereof; the main chain mesogen and the side chain mesogen are oriented in different directions, whereby a birefringence Δn of the optically anisotropic layer has reverse wavelength dispersion property; and retardations of a layer obtained by curing a composition (A0) in which the polymerizable monomer in the composition (A) is replaced by the polymerizable liquid crystal compound with reverse wavelength dispersion and retardations of the optically anisotropic layer satisfy specific relationship; and a circularly polarizing plate and a display device including the same.