[Cu2(3-{4-[4-(2,3-di-hydroxyphenyliminomethyl)anilinomethyl]phenyliminomethyl}-1,2-benzene-diol(2-))2] | 509083-98-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [Cu2(3-{4-[4-(2,3-di-hydroxyphenyliminomethyl)anilinomethyl]phenyliminomethyl}-1,2-benzene-diol(2-))2]
• CAS: 509083-98-1
• 化学式: C₅₈H₅₀Cu₂N₆O₈
• 分子量: 1086.16
• InChiKey: VHSMRSBPPZUOAP-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [Cu2(OAc)4(H2O)2] 、 2-(((4-((4-((2-hydroxy-3-methoxybenzylidene)amino)benzyl)amino)phenyl)imino)methyl)-6-methoxyphenol 以 乙醇 为溶剂， 以68%的产率得到[Cu2(3-{4-[4-(2,3-di-hydroxyphenyliminomethyl)anilinomethyl]phenyliminomethyl}-1,2-benzene-diol(2-))2]
  参考文献：
  名称：

  COMPLEXES OF TETRADENTATE SCHIFF BASE LIGANDS WITH DIVALENT TRANSITION METALS

  摘要：

  New homo-dinuclear metal complexes of the Schiff base ligands 2-{4-[4-(2-hydroxyphenyliminomethyl)anilinomethyl]-phenyliminomethyl} phenol (H2L1), 3-{4-[4-(2,3-di-hydroxy-phenyliminomethyl)anilinomethyl]phenyliminomethyl}- 1,2-benzene-diol (H2L2) and 4-bromo-2-{4-[4-(5-bromo-2-hydroxyphenyliminomethyl)anilinomethyl]phenyliminometh-y1}phenol (H2L3) have been prepared in EtOH solution and 2 were characterized by infrared, electronic and H-1 and C-13 NMR spectra, and by magnetic susceptibilities and molar conductivity measurements. The mass spectra of the Schiff base ligands were recorded. The ligands coordinate as neutral ligands via the Schiff base azomethine nitrogen and phenolic oxygen atoms. The keto-enol tautomeric forms of the Schiff base ligands H2L1, H2L2 and H2L3 have been investigated in polar and apolar organic solvents.

  DOI：

  10.1081/sim-120016471