| 169476-34-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 169476-34-0
• 化学式: C₅₄H₅₁As₂ReSn
• 分子量: 1154.76
• InChiKey: OUPZFPWFBGZRQY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.0
• 重原子数：
  58.0
• 可旋转键数：
  12.0
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为产物：
  描述：

  rhenium heptahydride;triphenylarsane 、 三苯基氢化锡 以 四氢呋喃 为溶剂， 以48%的产率得到
  参考文献：
  名称：

  Synthesis and reactivity of ReH7(AsPh3)2

  摘要：

  The synthesis of ReH7(AsPh(3))(2) is reported. Surprisingly, this complex appears to be a classical heptahydride and is remarkably resistant to substitution by nitrogen and phosphorus donor ligands. The reactivity of this polyhydride towards silanes and stannanes was also studied. The new complexes, ReH6(SiPh(3))(AsPh(3))(2) and ReH6(SnPh(3))(AsPh(3))(2), are formed with Ph(3)EH (E = Si,Sn) but ReH7(AsPh(3))(2) does not react with chelating silanes. These products appear to be more stable than their phosphine-supported analogues.

  DOI：

  10.1016/0020-1693(95)04628-m