α-Propyl-acrylsaeure-propylester | 3550-07-0

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: α-Propyl-acrylsaeure-propylester
• 英文别名: Propyl 2-methylidenepentanoate
• CAS: 3550-07-0
• 化学式: C₉H₁₆O₂
• 分子量: 156.225
• InChiKey: RKSMVZQEUFARRZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  11
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2-丙基丙烯酸 在 氯化亚砜 作用下， 生成 α-Propyl-acrylsaeure-propylester
  参考文献：
  名称：

  Marshalok, G.A.; Yatchishin, I. I.; Tolopko, D. K., Journal of Organic Chemistry USSR (English Translation), 1981, vol. 17, # 4, p. 603 - 608

  摘要：

  DOI：

文献信息

• Molecular Healing of Polymeric Materials, Coatings, Plastics, Elastomers, Composites, Laminates, Adhesives, and Sealants by Active Enzymes
  申请人：McDaniel C. Steven

  公开号：US20100210745A1

  公开（公告）日：2010-08-19

  Disclosed herein are polymeric materials such as a coating, a plastic, a laminate, a composite, an elastomer, an adhesive, or a sealant; a surface treatment such as a textile finish or a wax; a filler for such a polymeric material or a surface treatment that includes an enzyme such as an esterase (e.g., a lipolytic enzyme, a sulfuric ester hydrolase, an organophosphorus compound degradation enzyme), an enzyme (e.g., a lysozyme, a lytic transglycosylase) that degrades a cell wall and/or a cell membrane component, a biocidal or biostatic peotide, and/or a peptidase. Also disclosed herein are methods of altering a material's property such as service life, flexability, or rigidity, by incorporation of an enzyme into a material capable of being chemically crosslinked by the activity of a lipolytic enzyme, a hydrolase, and/or a urease.

  本文公开了一些聚合材料，如涂层、塑料、层压板、复合材料、弹性体、粘合剂或密封剂；一种表面处理，如纺织品涂层或蜡；一种填料，用于这样的聚合材料或表面处理，其中包括一种酶，如酯酶（例如，脂肪水解酶，硫酸酯水解酶，有机磷化合物降解酶），降解细胞壁和/或细胞膜成分的酶（例如，溶菌酶，裂解转糖基酶），生物杀菌或生物静态肽，以及/或肽酶。本文还公开了通过将酶纳入可通过脂肪水解酶、水解酶和/或脲酶的活性交联材料中来改变材料性能，如使用寿命、柔韧性或刚度的方法。
• Anti-fouling Paints and Coatings
  申请人：Reactive Surfaces LTD

  公开号：US20150191607A1

  公开（公告）日：2015-07-09

  Disclosed herein are polymeric materials such as a coating, a plastic, a laminate, a composite, an elastomer, an adhesive, or a sealant; a surface treatment such as a textile finish or a wax; a filler for such a polymeric material or a surface treatment that includes an enzyme such as an esterase (e.g., a lipolytic enzyme, a sulfuric ester hydrolase, an organophosphorus compound degradation enzyme), an enzyme (e.g., a lysozyme, a lytic transglycosylase) that degrades a cell wall and/or a cell membrane component, a biocidal or biostatic peptide, and/or a peptidase. Also disclosed herein are methods of altering a material's property such as service life, flexability, or rigidity, by incorporation of an enzyme into a material capable of being chemically crosslinked by the activity of a lipolytic enzyme, a hydrolase, and/or a urease.

  本文披露了聚合材料，例如涂层、塑料、层压材料、复合材料、弹性体、粘合剂或密封剂；表面处理，例如纺织品整理或蜡；填充剂，用于这种聚合材料或表面处理，包括酯酶（例如脂肪水解酶、硫酸酯水解酶、有机磷化合物降解酶）的酶，降解细胞壁和/或细胞膜成分的酶（例如溶菌酶、裂解转葡糖苷酶），生物杀菌或生物稳定肽，和/或肽酶。本文还披露了通过将酶并入能够通过脂肪水解酶、水解酶和/或脲酶的活性进行化学交联的材料中，改变材料性能（例如使用寿命、柔韧性或刚度）的方法。
• In-mold coating compositions containing a non-isocyanate-reactive unsaturated resin, a non-isocyanate-reactive monomer and a free isocyanate-containing compound
  申请人：ICI AMERICAS INC.

  公开号：EP0048117A2

  公开（公告）日：1982-03-24

  Fully cured reinforced molded resins such as polyester, polyurea-urethane, polyurea, polyurethane, polyisocyanurate, polyepoxy and polycarbonate resins can be in-mold coated to cover surface defects such as sink marks and microcracks with an improved coating composition comprising 5-94% by weight of an ethylenically unsaturated base resin free of groups reactive with isocyanate radicals; 5-94% by weight of an ethylenically unsaturated monomer free of groups reactive with isocyanate radicals; and 1-20% by weight of isocyanate-containing compounds or compounds which decompose to form free isocyanate-containing compounds. Such coatings unexpectedly have improved adherence to molded articles over those obtained from similar compositions which contain no free isocyanate. The compositions may contain minor amounts of emulsifiers, fillers, catalysts, cross-linking agents, dryers and pigments. In particular, the coatings obtained when the compositions contain electroconductive fillers can be painted by standard electrostatic paint techniques.

  聚酯、聚脲-聚氨酯、聚脲、聚氨酯、聚异氰尿酸酯、聚环氧树脂和聚碳酸酯树脂等完全固化的增强模塑树脂可进行模内涂覆，以覆盖表面缺陷，如凹痕和微裂纹，涂覆组合物的改良成分包括 5-94%（重量百分比）不含异氰酸酯基反应基团的乙烯基不饱和基树脂；5-94% （按重量计）不含异氰酸酯基反应基团的乙烯基不饱和单体；以及 1-20% （按重量计）含异氰酸酯的化合物或可分解形成游离异氰酸酯化合物的化合物。与不含游离异氰酸酯的类似组合物相比，这种涂料意外地改善了与成型物品的粘附性。组合物中可能含有少量乳化剂、填料、催化剂、交联剂、干燥剂和颜料。尤其是，当组合物中含有导电填料时，所得到的涂层可以通过标准的静电喷涂技术进行喷涂。
• SURFACE BLUSH-RESISTANT, FIRE-RETARDANT POLYOLEFIN RESIN COMPOSITION
  申请人：NIPPON PETROCHEMICALS COMPANY, LIMITED

  公开号：EP0392024A1

  公开（公告）日：1990-10-17

  A fire-retardant polyolefin composition having an excellent surface blush resistance is obtained by compounding: 100 parts of a resin component containing as the major components: a) 99 to 60 wt % of a polyolefin resin and b) 1 to 40 wt % of an olefin polymer modified with an unsaturated carboxylic acid or its derivative; c) 5 to 200 parts of a fire-retardant; and d) (1) mineral oil, wax or a paraffin, (2) a higher fatty acid or its ester, amide or metal salt, (3) silicone, (4) a polyhydric alcohol partially esterified with fatty acid, or an alkylene oxide adduct of aliphatic alcohol, fatty acid, aliphatic amine, fatty acid amide, alkylphenol or alkylnaphthol, and (5) a fluorinated elastomer.

  一种阻燃聚烯烃组合物具有优异的耐表面灼烧性，是通过以下混合物获得的：100 份的树脂组分，其主要成分包括a) 99 至 60 重量百分比的聚烯烃树脂和 b) 1 至 40 重量百分比的用不饱和羧酸或其衍生物改性的烯烃聚合物； c) 5 至 200 重量百分比的阻燃剂；d) (1) 矿物油、蜡或石蜡，(2) 高级脂肪酸或其酯、酰胺或金属盐，(3) 硅酮，(4) 部分与脂肪酸酯化的多元醇，或脂肪醇、脂肪酸、脂肪胺、脂肪酸酰胺、烷基酚或烷基萘酚的氧化烯加合物，以及 (5) 氟化弹性体。
• Process for producing alpha, beta-unsaturated carboxylic acid esters and catalyst for use in such process
  申请人：Nippon Shokubai Co., Ltd.

  公开号：EP1123915A1

  公开（公告）日：2001-08-16

  Economical and efficient processes for producing an α, β-unsaturated carboxylic acid heterocycle-inserted ester and an α,β-unsaturated carboxylic acid polyheteroalkylene ester as well as a catalyst suited for use in economically and efficiently producing an α,β-unsaturated carboxylic acid ester are provided. The invention provides (1) a process for producing an α,β-unsaturated carboxylic acid ester which comprises reacting an α,β-unsaturated carboxylic acid ester with a heterocyclic compound, (2) a process for producing an α,β-unsaturated carboxylic acid ester which comprises reacting an α,β-unsaturated carboxylic acid with a heterocyclic compound in the presence of a polymerization inhibitor and a metal oxide catalyst, and (3) a catalyst for the production of an α,β-unsaturated carboxylic acid ester    comprising a metal oxide.

  本发明提供了经济、高效地生产α，β-不饱和羧酸杂环插入酯和α，β-不饱和羧酸聚异链烷烃酯的工艺，以及适用于经济、高效地生产α，β-不饱和羧酸酯的催化剂。 本发明提供 (1）一种生产α，β-不饱和羧酸酯的工艺，它包括使α，β-不饱和羧酸酯与杂环化合物反应、 (2) α，β-不饱和羧酸酯的生产工艺 其中包括使 α，β-不饱和羧酸与杂环化合物反应 在聚合抑制剂和金属氧化物催化剂存在下，以及 (3) α,β-不饱和羧酸酯生产催化剂 包括一种金属氧化物。