1,5-bis(p-toluenesulfonamido)naphthalene | 57159-76-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,5-bis(p-toluenesulfonamido)naphthalene
• 英文别名: NSC 144469；N,N'-naphthalene-1,5-diyl-bis-toluene-4-sulfonamide；N,N'-Naphthalin-1,5-diyl-bis-toluol-4-sulfonamid；1.5-Bis-(toluol-sulfonyl-(4)-amino)-naphthalin；1.5-Bis-tosylamino-naphthalin；N,N'-(naphthalene-1,5-diyl)bis(4-methylbenzenesulfonamide)；4-methyl-N-[5-[(4-methylphenyl)sulfonylamino]naphthalen-1-yl]benzenesulfonamide
• CAS: 57159-76-9
• 化学式: C₂₄H₂₂N₂O₄S₂
• 分子量: 466.582
• InChiKey: MIVPUXMNDCDKFL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.9
• 重原子数：
  32
• 可旋转键数：
  6
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  109
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  1,5-bis(p-toluenesulfonamido)naphthalene 在 氯 作用下， 以 溶剂黄146 为溶剂， 生成 1,4,5,8-四氯萘
  参考文献：
  名称：

  Reimlinger,H.; King,G., Chemische Berichte, 1962, vol. 95, p. 1043 - 1048

  摘要：

  DOI：
• 作为产物：
  描述：

  1,5-二硝基萘 在 吡啶 、 乙醇 、 水 、 铁粉 、 iron(II) sulfate 作用下， 生成 1,5-bis(p-toluenesulfonamido)naphthalene
  参考文献：
  名称：

  54. 1：5-和1：8-萘二胺及相关化合物的制备

  摘要：

  DOI：

  10.1039/jr9450000202

文献信息

• Synthesis, Photophysical Properties and Two‐Photon Absorption Study of Tetraazachrysene‐based N‐Heteroacenes
  作者：Gang Li、Shuaihua Wang、Shufan Yang、Guangfeng Liu、Pin Hao、Yusen Zheng、Guankui Long、Dandan Li、Yu Zhang、Wenbin Yang、Liang Xu、Weibo Gao、Qichun Zhang、Guanwei Cui、Bo Tang

  DOI：10.1002/asia.201801656

  日期：2019.5.15

  synthesized and fully characterized. Their photophysical, electrochemical and fluorescence properties were investigated, and they exhibited blue to green emission in the solid state. Interestingly, SDNU‐2 exhibited high solid photoluminescence quantum efficiencies (75.3 %), which is the highest value of N‐heteroacenes derivatives to date. Two‐photon absorption studies have been conducted by using the

  设计，合成并充分表征了以四氮杂ach烯单元为核心的三个新颖的N-杂并六苯分子（SDNU-1，SDNU-2和SDNU-3）。对它们的光物理，电化学和荧光性质进行了研究，并且它们在固态下表现出蓝色至绿色的发射。有趣的是，SDNU-2表现出很高的固体光致发光量子效率（75.3％），这是迄今为止N-杂并并苯衍生物的最高值。通过使用开孔和闭孔Z-san技术进行了两光子吸收研究。SDNU-3的双光子吸收截面显着增强，幅度高达700 GM（1 GM = 1×10-50  cm 4  s /光子）在800 nm的光激发下，这是迄今为止通过使用Z扫描实验测得的异并四苯系统的最大值。我们将结果归因于四极取代基的强电荷转移与四氮杂环丁烯核之间的充分电子偶联。我们的结果将为设计基于N-杂茂并核的新型高效双光子材料提供新的指导。
• Unravelling the Roles of Solvophobic Effects and π⋅⋅⋅π Stacking Interactions in the Formation of [2]Catenanes Featuring Di‐(N‐Heterocyclic Carbene) Building Blocks
  作者：Ya‐Wen Zhang、Ye Lu、Li‐Ying Sun、Patrick D. Dutschke、Ming‐Ming Gan、Le Zhang、Alexander Hepp、Ying‐Feng Han、F. Ekkehardt Hahn

  DOI：10.1002/anie.202312323

  日期：2023.12.11

  Different effects have been shown to control the formation of [2]catenanes with different bridges between pyridine donors. The formation of [2-IL](OTf)4 is aided by solvophobic effects and [3-IL](OTf)4 is stabilized by solvophobic effects and π⋅⋅⋅π stacking. The π⋅⋅⋅π stacking between the pyrene groups is essential for the formation of [4-IL](PF6)4 and [5-IL](PF6)4, where the enhanced stability of

  已显示出不同的效果可以控制吡啶供体之间具有不同桥的[2]环烷的形成。 [ 2-IL ](OTf) 4的形成受到疏溶剂效应的帮助，并且 [ 3-IL ](OTf) 4受到疏溶剂效应和 π⋅⋅⋅π 堆积的稳定。芘基团之间的 π⋅⋅⋅π 堆积对于形成 [ 4-IL ](PF 6 ) 4和 [ 5-IL ](PF 6 ) 4至关重要，其中 [ 5-IL ]( 增强的稳定性PF 6 ) 4基于更稳定的Au−C NHC键。
• Organic electroluminescence element
  申请人：Yamagata Promotional Organization for Industrial Technology

  公开号：EP2075305A2

  公开（公告）日：2009-07-01

  An organic EL element having one or a plurality of organic layers including a light emitting layer between a pair of electrodes is arranged such that at least one layer of the above-mentioned organic layers contains a compound as expressed by the following general formula (1) independently or as a mixture. (where, R1-R4 are selected from the group consisting of hydrogen, an alkyl group, a cycloalkyl group, an alkoxy group, a cycloalkoxy group, and an aryloxy group, and they may be the same groups or the groups different from one another, and A1-A4 are selected from the group consisting of a phenyl group which is either substituted or unsubstituted and a 5 or 6 member heterocyclic ring group which is either substituted or unsubstituted, and they may be the same groups or the groups different from one another.)

  有机电致发光元件具有一个或多个有机层，其中包括位于一对电极之间的发光层，其布置方式为上述有机层中至少有一层单独或作为混合物含有下式（1）表示的化合物。 (其中，R1-R4选自由氢、烷基、环烷基、烷氧基、环烷氧基和芳氧基组成的组，它们可以是相同的基团，也可以是彼此不同的基团；A1-A4选自由取代或未取代的苯基和取代或未取代的5或6个杂环组成的组，它们可以是相同的基团，也可以是彼此不同的基团)。
• ORGANIC THIN FILM TRANSISTOR AND METHOD FOR MANUFACTURING SAME
  申请人：Fujifilm Corporation

  公开号：EP3116031A1

  公开（公告）日：2017-01-11

  Provided are an organic thin-film transistor including: a gate electrode, an organic semiconductor layer, a gate insulating layer, a source electrode, and a drain electrode on a substrate, in which the organic semiconductor layer includes an organic semiconductor and a resin (C) having one or more groups selected from the group consisting of a group having fluorine atoms, a group having silicon atoms, an alkyl group having one or more carbon atoms or having two or more carbon atoms in a case of forming an alkoxycarbonyl group, a cycloalkyl group, an aralkyl group, an aryloxycarbonyl group, an aromatic ring group substituted with at least one alkyl group, and an aromatic ring group substituted with at least one cycloalkyl group; and a method for manufacturing an organic thin-film transistor including: applying a coating solution which contains the organic semiconductor and the resin (C) and causing the resin (C) to be unevenly distributed.

  提供了一种有机薄膜晶体管，包括基板上的栅电极、有机半导体层、栅绝缘层、源电极和漏电极，其中有机半导体层包括有机半导体和树脂 (C)，树脂 (C)具有一个或多个基团，这些基团选自具有氟原子的基团、具有硅原子的基团组成的组、具有一个或多个碳原子的烷基，或在形成烷氧基羰基、环烷基、芳烷基、芳氧基羰基、被至少一个烷基取代的芳环基和被至少一个环烷基取代的芳环基的情况下具有两个或多个碳原子的烷基；一种制造有机薄膜晶体管的方法，包括涂敷含有有机半导体和树脂（C）的涂层溶液，并使树脂（C）不均匀分布。
• SEMICONDUCTOR ELEMENT AND INSULATING-LAYER-FORMING COMPOSITION
  申请人：FUJIFILM Corporation

  公开号：EP3125277A1

  公开（公告）日：2017-02-01

  Provided is a semiconductor element having a semiconductor layer and an insulating layer adjacent to the semiconductor layer, in which the insulating layer is formed of a crosslinked product of a polymer compound having a repeating unit (IA) represented by the following General Formula (IA) and a repeating unit (IB) represented by the following General Formula (IB). In General Formula (IA), R1a represents a hydrogen atom, a halogen atom, or an alkyl group. L1a and L2a each independently represent a single bond or a linking group. X represents a crosslinkable group. m2a represents an integer of 1 to 5, and in a case where m2a is 2 or more, m2a number of X's may be the same or different from each other. m1a represents an integer of 1 to 5, and in a case where m1a is 2 or more, m1a number of (-L2a-(X)m2a)'s may be the same or different from each other. In General Formula (IB),' R1b represents a hydrogen atom, a halogen atom, or an alkyl group. L1b represents a single bond or a linking group, and Ar1b represents an aromatic ring. m1b represents an integer of 1 to 5.

  本发明提供了一种半导体元件，该元件具有半导体层和与半导体层相邻的绝缘层，其中绝缘层由聚合物化合物的交联产物形成，该聚合物化合物具有如下通式(IA)表示的重复单元(IA)和如下通式(IB)表示的重复单元(IB)。 通式（IA）中，R1a 代表氢原子、卤素原子或烷基。L1a 和 L2a 各自独立地代表单键或连接基团。X 代表可交联基团。m2a 代表 1 至 5 的整数，在 m2a 为 2 或 2 以上的情况下，m2a 中 X 的数目可以相同或不同。m1a 代表 1 至 5 的整数，在 m1a 为 2 或 2 以上的情况下，m1a 中 (-L2a-(X)m2a) 的数目可以相同或不同。通式（IB）中，' R1b 代表氢原子、卤素原子或烷基。L1b 代表单键或连接基团，Ar1b 代表芳香环。